81844
炔丙基三甲基硅烷
technical, ~85% (GC)
别名:
三甲基炔丙基硅烷, 三甲基炔丙硅烷
等级
technical
方案
~85% (GC)
包含
~0.5% 2,6-di-tert-butyl-4-methylphenol as stabilizer
杂质
~10% isomeric allenyltrimethylsilane in equilibrium
折射率
n20/D 1.413 (lit.)
n20/D 1.413
沸点
91-93 °C (lit.)
密度
0.753 g/mL at 25 °C (lit.)
运输
wet ice
储存温度
−20°C
SMILES字符串
C[Si](C)(C)CC#C
InChI
1S/C6H12Si/c1-5-6-7(2,3)4/h1H,6H2,2-4H3
InChI key
ULYLMHUHFUQKOE-UHFFFAOYSA-N
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其他说明
Equilibrium with allenyl-trimethylsilane; Starting material for preparing substituted propargyl-silanes; these are used for the Lewis acid-catalyzed introduction of allenyl groups in electrophiles; Selective preparation of (E)- and (Z)-olefins
警示用语：
Danger
危险分类
Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
23.0 °F - closed cup
闪点(°C)
-5 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
J. Slutsky et al.
Journal of the American Chemical Society, 95, 8678-8678 (1973)
P.M. Esch et al.
Tetrahedron Letters, 29, 367-367 (1988)
J. Pornet et al.
Journal of Organometallic Chemistry, 349, 43-43 (1988)
A.G. Angoh et al.
Journal of the Chemical Society. Chemical Communications, 534-534 (1985)
H. Hiemstra et al.
The Journal of Organic Chemistry, 50, 4014-4014 (1985)
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