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Merck
CN

81860

Sigma-Aldrich

丙炔酸

technical, ≥95% (T)

别名:

2-丙炔酸, 乙炔羧酸

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线性分子式:
HC≡CCOOH
化学文摘社编号:
分子量:
70.05
Beilstein:
878176
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
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等级

technical

方案

≥95% (T)

折射率

n20/D 1.431 (lit.)
n20/D 1.431

沸点

102 °C/200 mmHg (lit.)

mp

16-18 °C (lit.)

密度

1.135 g/mL at 20 °C
1.138 g/mL at 25 °C (lit.)

储存温度

2-8°C

SMILES字符串

OC(=O)C#C

InChI

1S/C3H2O2/c1-2-3(4)5/h1H,(H,4,5)

InChI key

UORVCLMRJXCDCP-UHFFFAOYSA-N

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Danger

危险分类

Acute Tox. 2 Dermal - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

136.4 °F - closed cup

闪点(°C)

58 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

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A gold-catalyzed intermolecular reaction of propiolic acids with alkenes led to a [4 + 2] annulation or enyne cross metathesis. The [4 + 2] annulation proceeds with net cis-addition with respect to alkenes and provides an expedient route to α,β-unsaturated
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Proceedings of the National Academy of Sciences of the United States of America, 107(47), 20184-20189 (2010-11-10)
The use of carbon dioxide as a renewable and environmentally friendly source of carbon in organic synthesis is a highly attractive approach, but its real world applications remain a great challenge. The major obstacles for commercialization of most current protocols
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Journal of the American Chemical Society, 131(15), 5667-5674 (2009-04-01)
The build/couple/pair strategy has yielded small molecules with stereochemical and skeletal diversity by using short reaction sequences. Subsequent screening has shown that these compounds can achieve biological tasks considered challenging if not impossible ('undruggable') for small molecules. We have developed
Yu Sung Chun et al.
The Journal of organic chemistry, 74(19), 7556-7558 (2009-09-26)
The Blaise reaction intermediate, generated in situ from Reformatsky reagent and nitrile, reacted with propiolates in a chemo- and regioselective manner to afford 2-pyridone derivatives in good to excellent yields.

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