88470
茴香硫醚
ReagentPlus®, ≥99%
别名:
甲基苯基硫醚
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关于此项目
线性分子式:
C6H5SCH3
化学文摘社编号:
分子量:
124.20
EC Number:
202-878-2
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
1904179
MDL number:
InChI key
HNKJADCVZUBCPG-UHFFFAOYSA-N
InChI
1S/C7H8S/c1-8-7-5-3-2-4-6-7/h2-6H,1H3
SMILES string
CSc1ccccc1
product line
ReagentPlus®
assay
≥99%
bp
188 °C (lit.)
mp
−15 °C (lit.)
density
1.057 g/mL at 20 °C (lit.)
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Other Notes
高效促进剂，用于酸催化裂解 N-Z、O-苄基和 O-甲基保护基团
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Warning
存储类别
10 - Combustible liquids
flash_point_f
163.4 °F - closed cup
flash_point_c
73 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1B
法规信息
新产品
此项目有
Chemical & Pharmaceutical Bulletin, 26, 2562-2562 (1978)
Journal of the Chemical Society. Chemical Communications, 101-101 (1980)
Y. Kiso et al.
Journal of the Chemical Society. Chemical Communications, 971-971 (1979)
Jeong Sik Lim et al.
Nature chemistry, 2(8), 627-632 (2010-07-24)
Chemical reactions that occur in the ground electronic state are described well by invoking the Born-Oppenheimer approximation, which allows their development to be rationalized by nuclear rearrangements that smoothly traverse an adiabatic potential energy surface. The situation is different, however
Yunho Lee et al.
Inorganic chemistry, 49(19), 8873-8885 (2010-09-09)
To better understand the effect of thioether coordination in copper-O(2) chemistry, the tetradentate N(3)S ligand L(ASM) (2-(methylthio)-N,N-bis((pyridin-2-yl)methyl)benzenamine) and related alkylether ligand L(EOE) (2-ethoxy-N,N-bis((pyridin-2-yl)methyl)ethanamine) have been studied. The corresponding copper(I) complexes, [(L(ASM))Cu(I)](+) (1a) and [(L(EOE))Cu(I)](+) (3a), were studied as were the
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