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Merck
CN

88810

硫脲

puriss. p.a., ACS reagent, ≥99.0%

别名:

Sulfourea, 硫代尿素

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关于此项目

线性分子式:
NH2CSNH2
化学文摘社编号:
分子量:
76.12
EC Number:
200-543-5
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
605327
MDL number:
Assay:
≥99.0%
Form:
crystals
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grade

ACS reagent, puriss. p.a.

assay

≥99.0%

form

crystals

ign. residue

≤0.1% (as SO4)

loss

≤0.5% loss on drying, 105°C, 2h

mp

170-176 °C (lit.), 174-177 °C

solubility

water: soluble 137 g/L at 20 °C

anion traces

sulfate (SO42-): ≤100 mg/kg

cation traces

Cd: ≤5 mg/kg, Co: ≤5 mg/kg, Cr: ≤5 mg/kg, Cu: ≤5 mg/kg, Fe: ≤5 mg/kg, K: ≤50 mg/kg, Mg: ≤10 mg/kg, Mn: ≤5 mg/kg, Na: ≤50 mg/kg, Ni: ≤5 mg/kg, Pb: ≤5 mg/kg, Zn: ≤5 mg/kg

SMILES string

NC(N)=S

InChI

1S/CH4N2S/c2-1(3)4/h(H4,2,3,4)

InChI key

UMGDCJDMYOKAJW-UHFFFAOYSA-N

Gene Information

mouse ... Ephx2(13850)

Application

Thiourea may be used in the synthesis of thiobarbiturates and graphitic carbon nitride (g-C3N4).
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Warning

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 2 - Repr. 2

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

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Polycondensation of thiourea into carbon nitride semiconductors as visible light photocatalysts.
Zhang G, et al.
Journal of Materials Chemistry, 22(16), 8083-8091 (2012)
Adam R Brown et al.
Journal of the American Chemical Society, 135(18), 6747-6749 (2013-04-20)
Catalysis of Cope-type rearrangements of bis-homoallylic hydroxylamines is demonstrated using chiral thiourea derivatives. This formal intramolecular hydroamination reaction provides access to highly enantioenriched α-substituted pyrrolidine products and represents a complementary approach to metal-catalyzed methods.
The dissolution of gold in acidic solutions of thiourea.
Groenewald T.
Hydrometallurgy, 1(3), 277-290 (1976)