88810
硫脲
puriss. p.a., ACS reagent, ≥99.0%
别名:
Sulfourea, 硫代尿素
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关于此项目
线性分子式:
NH2CSNH2
化学文摘社编号:
分子量:
76.12
EC Number:
200-543-5
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
605327
MDL number:
Assay:
≥99.0%
Form:
crystals
InChI key
UMGDCJDMYOKAJW-UHFFFAOYSA-N
InChI
1S/CH4N2S/c2-1(3)4/h(H4,2,3,4)
SMILES string
NC(N)=S
grade
ACS reagent, puriss. p.a.
assay
≥99.0%
form
crystals
ign. residue
≤0.1% (as SO4)
loss
≤0.5% loss on drying, 105°C, 2h
Gene Information
mouse ... Ephx2(13850)
mp
174-177 °C
solubility
water: soluble 137 g/L at 20 °C
anion traces
sulfate (SO42-): ≤100 mg/kg
cation traces
Cd: ≤5 mg/kg, Co: ≤5 mg/kg, Cr: ≤5 mg/kg, Cu: ≤5 mg/kg, Fe: ≤5 mg/kg, K: ≤50 mg/kg, Mg: ≤10 mg/kg, Mn: ≤5 mg/kg, Na: ≤50 mg/kg, Ni: ≤5 mg/kg, Pb: ≤5 mg/kg, Zn: ≤5 mg/kg
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Application
离液剂；强变性剂。增加蛋白质的溶解性和回收率
Thiourea may be used in the synthesis of thiobarbiturates and graphitic carbon nitride (g-C3N4).
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 2 - Repr. 2
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
危险化学品
此项目有
Polycondensation of thiourea into carbon nitride semiconductors as visible light photocatalysts.
Zhang G, et al.
Journal of Materials Chemistry, 22(16), 8083-8091 (2012)
Eagleson M.
Concise Encyclopedia Chemistry, 115-115 (1994)
The dissolution of gold in acidic solutions of thiourea.
Groenewald T.
Hydrometallurgy, 1(3), 277-290 (1976)
Adam R Brown et al.
Journal of the American Chemical Society, 135(18), 6747-6749 (2013-04-20)
Catalysis of Cope-type rearrangements of bis-homoallylic hydroxylamines is demonstrated using chiral thiourea derivatives. This formal intramolecular hydroamination reaction provides access to highly enantioenriched α-substituted pyrrolidine products and represents a complementary approach to metal-catalyzed methods.
Yoshiji Takemoto
Chemical & pharmaceutical bulletin, 58(5), 593-601 (2010-05-13)
We have developed several multifunctional thiourea catalysts bearing a tertiary amine or an 1,2-amino alcohol in expectation of their synchronous activation of a nucleophile and an electrophile through both acid-base and hydrogen-bonding interactions. From these studies, it was revealed that
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