89021
硫酚
purum, ≥98.0% (GC)
别名:
巯基苯, 苯硫酚
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关于此项目
线性分子式:
C6H5SH
化学文摘社编号:
分子量:
110.18
EC Number:
203-635-3
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
506523
MDL number:
InChI key
RMVRSNDYEFQCLF-UHFFFAOYSA-N
InChI
1S/C6H6S/c7-6-4-2-1-3-5-6/h1-5,7H
SMILES string
Sc1ccccc1
vapor density
3.8 (vs air)
vapor pressure
1.4 mmHg ( 20 °C)
grade
purum
assay
≥98.0% (GC)
bp
169 °C (lit.)
mp
−15 °C (lit.)
density
1.073 g/mL at 25 °C (lit.)
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signalword
Danger
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 3 - Repr. 2 - Skin Irrit. 2
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
122.0 °F - closed cup
flash_point_c
50 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
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Run Zhang et al.
Bioconjugate chemistry, 23(4), 725-733 (2012-03-23)
Ruthenium(II) complexes have rich photophysical attributes, which enable novel design of responsive luminescence probes to selectively quantify biochemical analytes. In this work, we developed a systematic series of Ru(II)-bipyrindine complex derivatives, [Ru(bpy)(3-n)(DNP-bpy)(n)](PF(6))(2) (n = 1, 2, 3; bpy, 2,2'-bipyridine; DNP-bpy
Dnyaneshwar Kand et al.
The Analyst, 137(17), 3921-3924 (2012-07-04)
A BODIPY-based selective thiophenol probe capable of discriminating aliphatic thiols is reported. The fluorescence off-on effect upon reaction with thiol is elucidated with theoretical calculations. The sensing of thiophenol is associated with a color change from red to yellow and
Goutam Nandi et al.
Inorganic chemistry, 51(11), 6412-6420 (2012-05-25)
A new route is developed for the synthesis of molybdenum and tungsten porphyrins using [M(NO)(2)py(2)Cl(2)] (M = Mo, W) as the metal source and TPP (dianion of 5,10,15,20-meso-tetraphenylporphyrin) in the benzoic acid melt. Complexes [Mo(V)O(TPP)(OOCPh)] (1) and [W(V)O(TPP)(OOCPh)] (2) are
F P Cometto et al.
Langmuir : the ACS journal of surfaces and colloids, 28(38), 13624-13635 (2012-09-06)
The preparation and thermal stability of benzenethiol and benzeneselenol self-assembled monolayers (SAMs) grown on Au(111) have been investigated by electrochemical experiments and high-resolution photoemission spectroscopy. Both techniques confirm the formation of monolayers with high packing densities (θ = 0.27-0.29 ML)
Chuan Dai et al.
Chemical communications (Cambridge, England), 48(43), 5367-5369 (2012-04-25)
A ligand-free CuI-catalyzed cascade C-S and C-N cross coupling of (hetero)aryl ortho-dihalides and ortho-aminobenzenethiols has been developed, and various phenothiazines were synthesized with excellent regioselectivity. A possible mechanism is proposed for the cascade coupling.
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