主要文件

查看所有文档

89172

双(2,2,2-三氯乙基)磷酰氯

Name: 双(2,2,2-三氯乙基)磷酰氯
Brand: SIAL

purum, ≥98.0% (AT)

登录查看组织和合同定价。

选择尺寸

变更视图

关于此项目

线性分子式:

(Cl₃CCH₂O)₂P(O)Cl

化学文摘社编号:

17672-53-6

分子量:

379.22

EC Number:

241-650-7

UNSPSC Code:

12352100

PubChem Substance ID:

24889187

Beilstein/REAXYS Number:

1820707

MDL number:

MFCD00000809

技术服务

需要帮助？我们经验丰富的科学家团队随时乐意为您服务。

让我们为您提供帮助

grade

purum

assay

≥98.0% (AT)

mp

45-47 °C (lit.)

SMILES string

ClC(Cl)(Cl)COP(Cl)(=O)OCC(Cl)(Cl)Cl

InChI

1S/C4H4Cl7O3P/c5-3(6,7)1-13-15(11,12)14-2-4(8,9)10/h1-2H2

InChI key

ZHHCWQGVXYGWCW-UHFFFAOYSA-N

Other Notes

可在酪氨酸上引入受(2,2,2-三氯)乙基保护的磷酸酯的结构单元；用于保护磷酸丝氨酸

法规信息

新产品

此项目有

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

It looks like we've run into a problem, but you can still download Certificates of Analysis from our 文件 section.

如需帮助，请联系客户支持

已有该产品？

在文件库中查找您最近购买产品的文档。

访问文档库

Further studies on the use of 2,2,2-trichloroethyl groups for phosphate protection in phosphoserine peptide synthesis.

A Paquet

International journal of peptide and protein research, 39(1), 82-86 (1992-01-01)

Boc-Ser(PO3Tc2)-OH, Z-Ser(PO3Tc2)-OH and Fmoc-Ser(PO3Tc2)-OH, derivatives useful for peptide synthesis, have been obtained in high yields by acylation of H-Ser(PO3Tc2)-OH.CF3COOH. The latter was obtained from Boc- or Z-Ser(PO3Tc2)-OBzl by simultaneous removal of the amino- and carboxy-protecting groups by Pd-catalyzed hydrogenolysis in

Synthesis of phosphotyrosine-containing peptides using bis-(2,2,2-trichloro)ethyl groups for phosphate protection.

A Paquet et al.

The journal of peptide research : official journal of the American Peptide Society, 50(4), 262-268 (1997-11-14)

Suitability of bis-(2,2,2-trichloro)ethyl (Tc) groups for protection of phosphate moiety in Boc-mode synthesis of phosphotyrosine peptides is demonstrated Boc-Tyr(PO3Tc2)-OH and Fmoc-Tyr(PO3Tc2)-OH were prepared by acylating H-Tyr(PO3Tc2)-OH with (Boc)2O and Fmoc-ONSu, respectively. Phosphorus introduction was achieved by phosphorylating Boc-Tyr-OBzl with Tc

我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.

联系客户支持