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Merck
CN

90161

联呋喃甲酰二肟

for spectrophotometric det. of Au(II), Co(II), Cu(II), Ni(II), Pd(II), Re(VII), U(VI), ≥97.0% (sum of isomers, HPLC)

别名:

糠偶酰二肟

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经验公式(希尔记法):
C10H8N2O4
化学文摘社编号:
分子量:
220.18
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
41115716
EC Number:
208-326-7
MDL number:
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InChI key

RBOZTFPIXJBLPK-WGDLNXRISA-N

InChI

1S/C10H8N2O4/c13-11-9(7-3-1-5-15-7)10(12-14)8-4-2-6-16-8/h1-6,13-14H/b11-9+,12-10+

SMILES string

O\N=C(c1ccco1)\C(=N\O)c2ccco2

description

mixture of isomers

assay

≥97.0% (sum of isomers, HPLC)

form

crystals

technique(s)

UV/Vis spectroscopy: suitable

Quality Level

General description

Oximes are selective reagents which react with limited number of metal ions. These form water-insoluble complexes extractable into organic solvents. Furildioxime, a gravimetric and colorimetric reagent for nickel, palladium, platinum and rhenium is prepared by the oximation of furil with hydroxyammonium chloride followed by aqueous recrystallisation using MacKair′s method.

Application

a-furildioxime [(2,2′)-Furildioxime] was used:
  • as neutral carrier in Calcium(II)-selective potentiometric sensor, selective electrode used for titration.
  • in the synthesis of ketenimines and bis(ketenimines).
  • in determination of palladium in water samples by rapid spectrophotometric analysis.

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H Mitani et al.
European journal of pharmacology, 411(1-2), 169-174 (2001-01-04)
Kojic acid, a fungal metabolic product, has been used as a skin-depigmenting agent in skin care products marketed in Japan. Iron in the skin is known to be involved in wrinkling as a result of chronic photodamage. Kojic acid was
Najma Memon et al.
TheScientificWorldJournal, 2012, 418047-418047 (2012-06-02)
A very simple, selective, and fast flow injection spectrophotometeric method is developed for determination of nickel using furildioxime as complexing agent. Micellar solution of brij-35 is employed to solubilize the sparingly soluble complex of Ni-furildioxime in buffered aqueous system (pH-9.00).
D L Bissett et al.
Journal of the American Academy of Dermatology, 31(4), 572-578 (1994-10-01)
In previous work we found that iron is a factor in skin photodamage, apparently by way of its participation in oxygen radical production. Here we report topical photoprotection with the iron chelator 2-furildioxime (FDO). Our purpose was to determine the
Calcium (II)-selective potentiometric sensor based on a-furildioxime as neutral carrier.
Singh, Ashok Kumar, and Sameena Mehtab.
Sensors and Actuators B, Chemical, 123, 429-436 (2007)
Single-Channel Flow Injection Spectrophotometric Determination of Nickel Using Furildioxime in Micellar Solution.
Memon, Najma, et al.
TheScientificWorldJournal, 12, 1-5 (2012)

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