grade
purum
assay
≥95.0% (GC)
reaction suitability
reagent type: ligand
refractive index
n20/D 1.413
bp
156 °C (lit.)
density
0.969 g/mL at 25 °C (lit.)
functional group
phosphine
SMILES string
CCOP(OCC)OCC
InChI
1S/C6H15O3P/c1-4-7-10(8-5-2)9-6-3/h4-6H2,1-3H3
InChI key
BDZBKCUKTQZUTL-UHFFFAOYSA-N
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Other Notes
该亚磷酸酯的活性低于三苯基膦,但所得产物中的非对映体比例更好
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3 - Flam. Liq. 3 - Skin Sens. 1B
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
129.2 °F - closed cup
flash_point_c
54 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
C.A. Townsend, L.T. Nguyen
Tetrahedron Letters, 23, 4859-4859 (1982)
A.K. Bose et al.
Canadian Journal of Chemistry, 62, 2498-2498 (1984)
Rocky J Barney et al.
The Journal of organic chemistry, 76(8), 2875-2879 (2011-03-17)
Benzyl phosphonate esters often serve as reagents in Horner-Wadsworth-Emmons reactions. In most cases, they can be prepared from benzylic alcohols via formation of the corresponding halide followed by an Arbuzov reaction. To identify a more direct synthesis of phosphonate esters
Lu Gan et al.
Biomaterials, 25(22), 5303-5312 (2004-04-28)
Thin sol-gel-formed calcium phosphate (Ca-P) films were formed on sintered porous-surfaced implants as an approach to increasing the rate of bone ingrowth. The films were prepared using either an inorganic precursor solution (with calcium nitrate tetrahydrate and ammonium dihydrogen phosphate)
Triethyl phosphite mediated domino reaction: direct conversion of omega-nitroalkenes into N-heterocycles.
Elena Merişor et al.
Angewandte Chemie (International ed. in English), 46(18), 3353-3355 (2007-03-21)
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