90610
1,4,7-三氮杂环壬烷
purum, ≥97.0% (GC)
别名:
三乙基烯三胺, 八氢-1H-1,4,7-三偶氮宁
等级
purum
方案
≥97.0% (GC)
杂质
≤2% water
沸点
110-130 °C/7 mmHg (lit.)
mp
42-45 °C (lit.)
42-45 °C
SMILES字符串
C1CNCCNCCN1
InChI
1S/C6H15N3/c1-2-8-5-6-9-4-3-7-1/h7-9H,1-6H2
InChI key
ITWBWJFEJCHKSN-UHFFFAOYSA-N
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应用
有可能应用于具有高阳离子结合选择性的络合滴定。
其他说明
氮杂大环类化合物，适用于合成带侧臂的衍生物
警示用语：
Danger
危险声明
危险分类
Skin Corr. 1B
储存分类代码
8B - Non-combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
230.0 °F - closed cup
闪点(°C)
110 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
此项目有
T.A. Kaden
Topics in Current Chemistry, 121, 157-157 (1984)
Meite Xin et al.
Chembiochem : a European journal of chemical biology, 11(2), 272-276 (2009-12-17)
Substituted 2-tropolone natural products are found in plants and fungi. Their biosynthesis is thought to occur by ring expansion from a cyclohexadienone precursor, but this reaction has not previously been demonstrated experimentally. Treatment of 6-hydroxy-6-hydroxymethylcyclohexa-2,4-dienone with the non-haem iron(II)-dependent extradiol
Jakub Šimeček et al.
Inorganic chemistry, 51(1), 577-590 (2012-01-10)
Three phosphinic acid 1,4,7-triazacyclononane (TACN) derivatives bearing methylphosphinic (TRAP-H), methyl(phenyl)phosphinic (TRAP-Ph), or methyl(hydroxymethyl)phosphinic acid (TRAP-OH) pendant arms were investigated as members of a new family of efficient Ga(3+) chelators, TRAP ligands (triazacyclononane phosphinic acids). Stepwise protonation constants of ligands and
Bim Graham et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 879(13-14), 844-852 (2011-03-25)
The protein binding characteristics of the immobilized binucleating chelate system, 1,4-bis(1,4,7-triazacyclononan-1-yl)butane (tacn(2)butane), complexed with Cu(2+) ions have been investigated with hen egg white lysozyme, horse skeletal muscle myoglobin and horse heart cytochrome C, as well as three histidine-rich proteins, serum
Qin-Fang Zhang et al.
Bioorganic & medicinal chemistry letters, 21(23), 7045-7049 (2011-10-19)
A series of novel cationic lipids based on 1,4,7-triazacyclononane (TACN) with different hydrophobic chains were synthesized via the formation of a biodegradable ester bond. These lipids were found to have good buffering capacity at the pH range of 5.0-6.5, which
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