90610
1,4,7-三氮杂环壬烷
purum, ≥97.0% (GC)
别名:
三乙基烯三胺, 八氢-1H-1,4,7-三偶氮宁
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关于此项目
经验公式（希尔记法）:
C6H15N3
化学文摘社编号:
分子量:
129.20
PubChem Substance ID:
UNSPSC Code:
12350000
Beilstein/REAXYS Number:
773877
MDL number:
SMILES string
C1CNCCNCCN1
InChI
1S/C6H15N3/c1-2-8-5-6-9-4-3-7-1/h7-9H,1-6H2
InChI key
ITWBWJFEJCHKSN-UHFFFAOYSA-N
grade
purum
assay
≥97.0% (GC)
impurities
≤2% water
bp
110-130 °C/7 mmHg (lit.)
Application
有可能应用于具有高阳离子结合选择性的络合滴定。
Other Notes
氮杂大环类化合物，适用于合成带侧臂的衍生物
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8B - Non-combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
此项目有
Meite Xin et al.
Chembiochem : a European journal of chemical biology, 11(2), 272-276 (2009-12-17)
Substituted 2-tropolone natural products are found in plants and fungi. Their biosynthesis is thought to occur by ring expansion from a cyclohexadienone precursor, but this reaction has not previously been demonstrated experimentally. Treatment of 6-hydroxy-6-hydroxymethylcyclohexa-2,4-dienone with the non-haem iron(II)-dependent extradiol
Natascha Ghaschghaie et al.
Dalton transactions (Cambridge, England : 2003), 39(23), 5535-5543 (2010-05-18)
Co(III)(tacn) and Ga(III)(tacn) fragments (tacn = 1,4,7-triazacyclononane) are suitable metal probes for the detection of the tridentate chelating sites of a glycose. Three moles of hydroxide per mole of cobalt or gallium support triple deprotonation of the chelating triol functions
Jane T Mooney et al.
Journal of chromatography. A, 1218(1), 92-99 (2010-12-17)
This study describes the screening of a peptide phage display library for amino acid sequences that bind with different affinities to a novel class of chelating ligands complexed with Ni²+ ions. These chelating ligands are based on the 1,4,7-triazacyclononane (TACN)
Christopher C Scarborough et al.
Inorganic chemistry, 50(24), 12446-12462 (2011-11-17)
The electron transfer series of complexes [Cr((t)bpy)(3)](n)(PF(6))(n) (n = 3+, 2+, 1+, 0 (1-4)) has been synthesized and the molecular structures of 1, 2, and 3 have been determined by single-crystal X-ray crystallography; the structure of 4 has been investigated
Yu Chen et al.
Talanta, 83(1), 145-148 (2010-11-03)
The electrochemistry of a macrocyclic metal complex Fe(notpH(3)) [notpH(6)=1,4,7-triazacyclononane-1,4,7-triyl-tris(methylene-phosphonic acid)] reveals that the protonation/deprotonation of the non-coordinated P-OH groups in Fe(notpH(3)) affects its formal potential value (E(0)') considerably. Plotting E(0)' as function of solution pH gives a straight line with
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