92080
1-(2,4,6-三异丙基苯磺酰基)-4-硝基咪唑
purum, ≥98.0% (HPLC)
别名:
TPSNI
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关于此项目
经验公式（希尔记法）:
C18H25N3O4S
化学文摘社编号:
分子量:
379.47
PubChem Substance ID:
UNSPSC Code:
12352200
Beilstein/REAXYS Number:
583013
MDL number:
SMILES string
CC(C)c1cc(C(C)C)c(c(c1)C(C)C)S(=O)(=O)n2cnc(c2)[N+]([O-])=O
InChI
1S/C18H25N3O4S/c1-11(2)14-7-15(12(3)4)18(16(8-14)13(5)6)26(24,25)20-9-17(19-10-20)21(22)23/h7-13H,1-6H3
InChI key
ZYQZZMOLYGORFJ-UHFFFAOYSA-N
grade
purum
assay
≥98.0% (HPLC)
mp
157-159 °C (sealed tube)
storage temp.
−20°C
Other Notes
用于寡核苷酸合成的缩合试剂
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
J H van Boom et al.
Nucleic acids research, 4(4), 1047-1063 (1977-04-01)
A combination of two different methods for the synthesis of oligoribonucleotides, i.e. the two-step phosphotriester method with 2-chlorophenyl phosphate as bifunctional phosphate source and the modified triester method with 2,2,2-trichloroethyl 2-chlorophenyl phosphorochloridate as monofunctional phosphate source, is applied for the
J.F.M. de Rooij et al.
Tetrahedron, 35, 2913-2913 (1979)
K K Ogilvie et al.
Nucleic acids research, 8(9), 2105-2115 (1980-05-10)
The t-butyldimethylsilyl group is shown to be an ideal protecting group for the 2T-hydroxyl function of ribonucleosides during the synthesis of ribonucleotides using any of nine commonly used condensing agents. The phosphite coupling procedure compares favorably with all of the
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