93098
三苯基膦氢溴酸盐
purum, ≥96.0% (T)
别名:
Ph3P · HBr, 三苯基溴化膦
等级
purum
方案
≥96.0% (T)
反应适用性
reagent type: ligand
mp
196 °C (dec.) (lit.)
官能团
phosphine
SMILES字符串
Br.c1ccc(cc1)P(c2ccccc2)c3ccccc3
InChI
1S/C18H15P.BrH/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h1-15H;1H
InChI key
CMSYDJVRTHCWFP-UHFFFAOYSA-N
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其他说明
由烯丙醇直接制备烯丙基磷鎓盐的温和试剂;缩醛、醚和酯裂解的酸性催化剂;形成叔醇的 THP-醚;溴化氢气体的简便和定量来源
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
此项目有
P.A. Grieco et al.
The Journal of Organic Chemistry, 53, 3658-3658 (1988)
H R Sliwka et al.
Acta chemica Scandinavica. Series B: Organic chemistry and biochemistry, 41(4), 245-252 (1987-04-01)
The structure of a sponge metabolite from Microciona prolifera, previously considered to be (6S)-2,3-didehydro- or 3,4-didehydro-gamma, chi-carotene, has been further studied. Attempted total synthesis of the 3,4-didehydro derivative provided the hitherto unknown gamma, chi-carotene, the synthesis of which is described.
V. Bolitt et al.
Tetrahedron Letters, 29, 4583-4583 (1988)
A. Hercouet et al.
Synthesis, 157-157 (1988)
H.J. Bestmann et al.
Justus Liebigs Annalen der Chemie, 709, 105-105 (1967)
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