B2633
叔丁基过氧化氢 溶液
70% in H2O
别名:
1,1-二甲基乙基-过氧化氢, 2-过氧化氢-2-甲基丙烷, TBHP
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线性分子式:
(CH3)3COOH
化学文摘社编号:
分子量:
90.12
UNSPSC Code:
12162002
Beilstein/REAXYS Number:
1098280
MDL number:
InChI key
CIHOLLKRGTVIJN-UHFFFAOYSA-N
SMILES string
CC(C)(C)OO
InChI
1S/C4H10O2/c1-4(2,3)6-5/h5H,1-3H3
reaction suitability
reagent type: oxidant
concentration
70% in H2O
density
0.94 g/mL at 25 °C (lit.)
storage temp.
2-8°C
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Other Notes
This product has been replaced by 458139-ALDRICH | Luperox TBH70X, tert-Butyl hydroperoxide solution 70 wt. % in H2O
signalword
Danger
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Org. Perox. F - Skin Corr. 1C - Skin Sens. 1 - STOT SE 3
target_organs
Respiratory system
存储类别
5.2 - Organic peroxides and self-reacting hazardous materials
wgk
WGK 3
flash_point_f
109.4 °F - closed cup
flash_point_c
43 °C - closed cup
法规信息
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Yury Minko et al.
Nature protocols, 8(4), 749-754 (2013-03-23)
This protocol describes a new approach for the preparation of stereodefined trisubstituted chiral enolate species, avoiding conventional asymmetric enolization of carbonyl compounds. This protocol was developed as a single-flask synthetic sequence and therefore does not require isolation or purification of
Qicai Xue et al.
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A new synthetic approach toward direct C-N bond formation through sp(3) C-H activation has been developed under metal-free conditions. Both primary and secondary benzylic C-H substrates could react smoothly with various amines to give only mono-amination products with good to
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Oligomeric and polymeric procyanidins have been reported to possess different antioxidant capacities. However, the intracellular antioxidant mechanisms of oligomeric and polymeric procyanidins are still poorly understood. In this study, we evaluated the cytoprotective effects of the oligomeric procyanidin fraction (OPF)
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Qiong Tang et al.
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This work investigated the ultrasonic assisted oxidative desulfurization of bunker-C oil with TBHP/MoO3 system. The operational parameters for the desulfurization procedure such as ultrasonic irradiation time, ultrasonic wave amplitude, catalyst initial concentration and oxidation agent initial concentration were studied. The
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