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Merck
CN

CN205761

硝酸钯(II) 水合物

powder and chunks

别名:

硝酸亚钯 水合物, 硝酸钯 水合物

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线性分子式:
Pd(NO3)2·xH2O
化学文摘社编号:
分子量:
230.43 (anhydrous basis)
UNSPSC Code:
12161600
PubChem Substance ID:
MDL number:
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InChI

1S/2NO3.H2O.Pd/c2*2-1(3)4;;/h;;1H2;/q2*-1;;+2

SMILES string

O.[Pd++].[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI key

DTZRLFJKQHIVQA-UHFFFAOYSA-N

form

powder and chunks

Quality Level

reaction suitability

reaction type: Sonogashira Coupling, reagent type: catalyst
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: catalyst
core: palladium
reaction type: Heck Reaction, reagent type: catalyst
core: palladium
reaction type: Hiyama Coupling, reagent type: catalyst
core: palladium
reaction type: Negishi Coupling, reagent type: catalyst
core: palladium
reaction type: Stille Coupling, reagent type: catalyst
core: palladium
reaction type: Suzuki-Miyaura Coupling

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Application

用作以下过程的反应物:
  • 燃料电池耐甲醇氧还原铂钯/碳合金纳米催化剂的制备
  • 硝酸盐基电解槽共电沉积钯和铜在钛基体上合成铜钯合金薄膜
  • 垂直排列多壁碳纳米管负载钯催化剂的制备及对 对-碘硝基苯与苯乙烯、丙烯酸乙酯的赫克反应
  • 抗烧结 Pd/SiO2 纳米催化剂的制备
  • 乙炔加氢二苯硫醚改性 Pd/TiO2 催化剂的制备
  • 氧化铝负载钯催化巴豆醛气相加氢催化剂的合成
Application
Catalyst for alkene nitration to glycol dinitrates; also used as a precursor to supported Pd catalysts.
Reactant for:
1. Preparation of platinum-palladium/carbon alloy nanocatalysts for methanol-tolerant oxygen reduction reaction in fuel cells
2. Synthesis of Cu-Pd alloy thin films on Ti substrates by co-electrodeposition of Pd and Cu from nitrate-base electrolytic baths
3. Preparation of palladium catalyst supported on vertically aligned multi-walled carbon nanotubes for microwave-assisted Heck reactions of p-iodonitrobenzene with styrene and Et acrylate
4. Preparation of a sinter-resistant Pd/SiO2 nanocatalyst
5. Preparation of di-phenyl sulfide-modified Pd/TiO2 catalysts for acetylene hydrogenation
6. Synthesis of alumina-supported palladium catalysts active for the gas phase hydrogenation of crotonaldehyde

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