M2780
L-薄荷醇
ReagentPlus®, 99%
别名:
(-)-薄荷醇, (1R,2S,5R)-2-异丙基-5-甲基环己醇, 5-甲基-2-异丙基环己醇
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关于此项目
经验公式（希尔记法）:
C10H20O
化学文摘社编号:
分子量:
156.27
UNSPSC Code:
12352001
NACRES:
NA.22
PubChem Substance ID:
EC Number:
218-690-9
Beilstein/REAXYS Number:
1902293
MDL number:
Assay:
99%
Biological source:
synthetic (organic)
Solubility:
water: 20 mg/mL, clear, colorless
产品名称
L-薄荷醇, ReagentPlus®, 99%
InChI key
NOOLISFMXDJSKH-KXUCPTDWSA-N
InChI
1S/C10H20O/c1-7(2)9-5-4-8(3)6-10(9)11/h7-11H,4-6H2,1-3H3/t8-,9+,10-/m1/s1
SMILES string
CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O
biological source
synthetic (organic)
vapor pressure
0.8 mmHg ( 20 °C)
product line
ReagentPlus®
assay
99%
optical activity
[α]20/D −50°, c = 10 in 95% ethanol
optical purity
ee: 99% (GLC)
bp
212 °C (lit.)
mp
41-45 °C (lit.)
solubility
water: 20 mg/mL, clear, colorless
density
0.89 g/mL at 25 °C (lit.)
Quality Level
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Application
(1R,2S,5R)-(-)-薄荷醇可以用于以下合成：
- 手性对映纯 2-(1-羟烷基)吡啶，可以反应生成C3-对称三脚架配体
- 甲基偶磷二氯化物, 一种手性衍生剂，通过 31P NMR光谱，用来确定手性二醇类或二氨
- (2R,4S)-2,3,4,5-四羟基-2-(-)-甲氧基-2-甲基-4-苯基吡喃酮-[3,2-c]-苯并吡喃-5-酮,一种中间体用来制备华法林类似物
制备用于手性插烯 Darzens 和 Reformatsky 反应的试剂。用于酸的拆分以及立体控制合成的重要手性助剂。
General description
(1R,2S,5R)-(-)-薄荷醇是一种单萜。
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 1
flash_point_f
201.2 °F - closed cup
flash_point_c
94 °C - closed cup
Fieser, M.
Reagents for Organic Synthesis, 16, 203-203 (1992)
The Journal of Organic Chemistry, 52, 4397-4397 (1987)
A new 31P NMR method for the enantiomeric excess determination of diols and secondary diamines with C 2 symmetry.
Brunel JM and Faure B.
Tetrahedron Asymmetry, 6(9), 2353-2356 (1995)
Novel 2-(hydroxyalkyl) pyridines derived from the chiral pool.
Adolfsson H, et al.
Tetrahedron Asymmetry, 7(7), 1967-1972 (1996)
Marei GI, et al.
Pesticide Biochemistry and Physiology, 103(1), 56-61 (2012)
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