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Merck
CN

P6863

Sigma-Aldrich

PDAM

≥70% purity (HPLC), for HPLC derivatization, solid

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别名:
1-芘基重氮甲烷, 芘,1-(重氮甲烷), 芘,1-(重氮甲基)
经验公式(希尔记法):
C17H10N2
CAS号:
分子量:
242.27
MDL编号:
UNSPSC代码:
12171500
PubChem化学物质编号:
NACRES:
MA.02

等级

for HPLC derivatization

质量水平

检测方案

≥70% (HPLC)

形式

solid

λmax

338-344 nm

荧光

λem 371-379 nm

应用

diagnostic assay manufacturing
hematology
histology

运输

dry ice

储存温度

−20°C

SMILES字符串

[N-]=[N+]=Cc1ccc2ccc3cccc4ccc1c2c34

InChI

1S/C17H10N2/c18-19-10-14-7-6-13-5-4-11-2-1-3-12-8-9-15(14)17(13)16(11)12/h1-10H

InChI key

PEIBAWRLFPGPAT-UHFFFAOYSA-N

应用

荧光重氮烷,可用作羧酸检测的 HPLC 衍生化试剂,比常用的 9-蒽基重氮甲烷具有更佳的检测限参数以及更好的化学稳定性。

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WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)


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G A Mills et al.
Journal of chromatography. B, Biomedical sciences and applications, 730(1), 113-122 (1999-08-07)
Short chain fatty acids (SFCAs) are nutritionally important products of colonic bacteria. Their analysis in faeces is problematic. We report a headspace solid-phase microextraction procedure in which faecal SCFAs are derivatised on the fibre in-situ with 1-pyrenyldiazomethane. With this method
Vladimir B Ritov et al.
Analytical biochemistry, 311(1), 10-18 (2002-11-21)
F(2)-isoprostanes are produced during free radical oxidation of cell phospholipids and are considered reliable biomarkers of oxidative stress. Currently, mass spectroscopy is the method of choice to detect F(2)-isoprostanes. However, due to numerous isomeric forms, analysis of F(2)-isoprostanes using MS
Junko Amano et al.
Analytical chemistry, 82(20), 8738-8743 (2010-09-25)
Glycoproteomics holds the promise of new advances in medical technology. However, mass spectrometry has limitations for the structural determination of glycosylated peptides because the hydrophilic nature of the oligosaccharide moiety in glycopeptides is disadvantageous for ionization, and glycopeptides ionize much
F Iohan et al.
Journal of chromatography, 564(1), 27-41 (1991-03-08)
A new procedure is described for the detection of the acidic metabolites of cortisol (cortoic acids) as the pyrenylmethyl-21-oic esters. The derivatizing reagent, diazomethylpyrene, was prepared by an improved procedure. The reagent was used at room temperature, required no catalyst
Carlos García et al.
Biological research, 36(2), 171-183 (2003-09-30)
Diarrhetic shellfish poisoning (DSP) is a gastrointestinal disease caused by lipid soluble polyether toxins produced by dinoflagellates and accumulated in shellfish. Diarrhetic shellfish poisoning is a worldwide threat to public health and the shellfish industry. To date, only four lipid

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