PMC2016
2-(二叔丁基膦)联苯
≥98%, ISOM8™
别名:
(2-联苯基)二-叔丁基膦, 2-(二-叔-丁基膦基)联苯, JohnPhos
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关于此项目
线性分子式:
C6H5C6H4P[C(CH3)3]2
化学文摘社编号:
分子量:
298.40
UNSPSC Code:
12352002
Beilstein/REAXYS Number:
8322131
MDL number:
product line
ISOM8™
Quality Level
assay
≥98%
form
solid
purified by
HPLC
reaction suitability
reagent type: ligand, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: C-X Bond Formation, reagent type: ligand
reaction type: Cross Couplings, reagent type: ligand
reaction type: Heck Reaction, reagent type: ligand
reaction type: Suzuki-Miyaura Coupling
mp
86-88 °C (Lit.), 86-88 °C (lit.)
application(s)
diagnostic assay manufacturing
life science and biopharma
functional group
phosphine
storage temp.
room temp
SMILES string
CC(C)(C)P(c1ccccc1-c2ccccc2)C(C)(C)C
InChI
1S/C20H27P/c1-19(2,3)21(20(4,5)6)18-15-11-10-14-17(18)16-12-8-7-9-13-16/h7-15H,1-6H3
InChI key
CNXMDTWQWLGCPE-UHFFFAOYSA-N
General description
Welcome to our ISOM8™ line of high-quality products available and able to scale for manufacturing. Within our ISOM8 team, we have expertise and documentation to support ISO 9001 industrial and non-GMP pharma production needs, as defined by our M-Clarity™ Program.
Application
作为配体，其用于芳基卤化物和芳基三氟甲磺酸酯的胺化。
可催化：
可催化：
- 二烷氧基苯甲酸与二芳基二硫化物或二芳基二硒醚的脱羧交叉偶联
- 通过N-烯丙基-N-芳基脲的分子内加氢胺化，立体选择性制备咪唑烷酮
- 烯烃与芳基氯化物的区域选择性芳基化
- 用于合成多不饱和大环内酯的交叉偶联反应
- 区域选择性 O-烷基化反应
- Sonogashira型交叉偶联
Our portfolio of ISOM8™ products and chemistries is ever evolving to support our valued SIGMA-ALDRICH® customers′ requirements. Please navigate to our documents section to look at dossiers and other quality documentation for this product, provided with support of our Elevate Program.
Legal Information
ISOM8 is a trademark of Sigma-Aldrich Co. LLC
M-CLARITY is a trademark of Merck KGaA, Darmstadt, Germany
SIGMA-ALDRICH is a registered trademark of Merck KGaA, Darmstadt, Germany
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存储类别
11 - Combustible Solids
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
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全球贸易项目编号
| 货号 | GTIN |
|---|---|
| PMC2016-1G | 04065273843323 |
| PMC2016-100G | 04065273843316 |
| PMC2016-1KG | 04065273843330 |
| PMC2016-500G | 04065273843347 |
| PMC2016-5G | 04065273843354 |