11204
碳酸铵
puriss., meets analytical specification of NF, Ph. Franc., FCC
别名:
鹿角盐
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关于此项目
线性分子式:
(NH4)2CO3
化学文摘社编号:
分子量:
96.09
NACRES:
NA.21
PubChem Substance ID:
eCl@ss:
38020208
UNSPSC Code:
12352300
EC Number:
208-058-0
MDL number:
Beilstein/REAXYS Number:
4253487
Form:
powder or crystals
产品名称
碳酸铵, puriss., meets analytical specification of NF, Ph. Franc., FCC
InChI key
PRKQVKDSMLBJBJ-UHFFFAOYSA-N
InChI
1S/CH2O3.2H3N/c2-1(3)4;;/h(H2,2,3,4);2*1H3
SMILES string
N.N.OC(O)=O
vapor density
2.7 (vs air)
grade
puriss.
form
powder or crystals
quality
meets analytical specification of NF, Ph. Franc., FCC
concentration
30.0-34.0% (NH3 , titration)
impurities
residual solvents, complies
≤0.0005% heavy metals (as Pb)
≤0.05% non-volatile matter
ign. residue
≤0.05% (as SO4)
anion traces
chloride (Cl-): ≤10 mg/kg
sulfate (SO42-): ≤50 mg/kg
cation traces
As: ≤3 mg/kg
Fe: ≤5 mg/kg
Pb: ≤3 mg/kg
suitability
complies for appearance of solution
Quality Level
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Application
Ammonium carbonate may be employed in the preparation of 3,4-dihydropyrimidin-2(1H)-one and 1,4-dihydropyridine derivatives, via Biginelli and Hantzsch reactions. It can also be actively used as buffer in the separation, detection, and identification of the peptide fragments generated in the tryptic digests of ovalbumin and serum albumin, via size exclusion liquid chromatography and reverse phase liquid chromatography coupled to mass spectrometry.
General description
Ammonium carbonate is an ammonium salt. It is colorless and is composed of water soluble cubic crystals. It can be synthesized by reacting carbon dioxide with ammonia. It is widely employed as a CO2 source in fire extinguishers. Calorimetric estimation of enthalpies of absorption of CO2 in aqueous solutions of ammonium carbonate in the temperature range of 35-80°C have been reported.
存储类别
11 - Combustible Solids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
?Two-Dimensional SEC/RPLC Coupled to Mass Spectrometry for the Analysis of Peptides?
Opiteck.JG and Jorgenson.WJ
Journal of Analytical Chemistry, 69, 2283-2291 (1997)
Eagleson M.
Concise Encyclopedia Chemistry (1994)
Synthesis of 3, 4-dihydropyrimidin-2 (1H)-ones and 1, 4-dihydropyridines using ammonium carbonate in water.
Tamaddon F, et al.
Tetrahedron Letters, 51(8), 1187-1189 (2010)
A Polettini et al.
Journal of chromatography. B, Biomedical sciences and applications, 754(2), 447-459 (2001-05-08)
For the first time, an LC-MS-MS method has been developed for the simultaneous analysis of buprenorphine (BUP), norbuprenorphine (NBUP), and buprenorphine-glucuronide (BUPG) in plasma. Analytes were isolated from plasma by C18 SPE and separated by gradient RP-LC. Electrospray ionization and
Heat of absorption of CO2 in aqueous ammonia and ammonium carbonate/carbamate solutions.
Qin F, et al.
International Journal of Greenhouse Gas Control, 5(3), 405-412 (2011)
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