205303
高氯酸锂 三水合物
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关于此项目
线性分子式:
LiClO4 · 3H2O
化学文摘社编号:
分子量:
160.44
EC 号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.55
表单
crystals and lumps
反应适用性
reagent type: oxidant
浓度
21-22% (chlorine basis (silver nitrate titration))
密度
1.841 g/mL at 25 °C (lit.)
SMILES字符串
[Li+].[H]O[H].[H]O[H].[H]O[H].[O-]Cl(=O)(=O)=O
InChI
1S/ClHO4.Li.3H2O/c2-1(3,4)5;;;;/h(H,2,3,4,5);;3*1H2/q;+1;;;/p-1
InChI key
JAWYRNYHJJDXHX-UHFFFAOYSA-M
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一般描述
Crystal structure of lithium perchlorate trihydrate (LiClO4.3H2O) has been investigated by X-ray and neutron diffraction studies. It exhibits pyroelectric properties.
应用
当用作助催化剂时，可加速 Baylis-Hillman 反应以及 α,β-不饱和羰基化合物与醛的偶联。
Lithium perchlorate trihydrate may be used to modify the membrane morphology of poly[(vinylidene fluoride)-co-trifluoroethylene] membranes, by doping it with varying concentrations of LiClO4.3H2O. It may be used to compose the polymer nanocomposite electrolyte (PNCE) films.
警示用语：
Danger
危险分类
Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
5.1A - Strongly oxidizing hazardous materials
WGK
WGK 1
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
易制爆化学品
危险化学品
此项目有
Neutron diffraction refinement of pyroelectric lithium perchlorate trihydrate.
Lundgren JO, et al.
Acta Crystallographica Section B, Structural Crystallography and Crystal Chemistry, 38(1), 15-20 (1982)
Jian-Yu Lu et al.
Polymers, 13(3) (2021-01-28)
Hydroquinone (HQ) is one of the major deleterious metabolites of benzene in the human body, which has been implicated to cause various human diseases. In order to fabricate a feasible sensor for the accurate detection of HQ, we attempted to
The structure of lithium perchlorate trihydrate Li(H2O)3ClO4-an X-ray and neutron diffraction study.
Sequeira A, et al.
Acta Crystallographica Section B, Structural Crystallography and Crystal Chemistry, 31(6), 1735-1739 (1975)
Ionic conduction and relaxation processes in melt compounded poly(ethylene oxide)-lithium perchlorate trihydrate-montmorillonite nanocomposite electrolyte.
Choudhary S and Sengwa RJ.
Indian Journal of Engineering and Materials Sciences, 18(2), 147-156 (2011)
Effect of the microsctructure and lithium-ion content in poly [(vinylidene fluoride)-co-trifluoroethylene]/lithium perchlorate trihydrate composite membranes for battery applications.
Costa CM, et al.
Solid State Ionics, 217, 19-26 (2012)
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