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文件

安全信息

216232

Sigma-Aldrich

过硫酸钠

reagent grade, ≥98%

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别名:
过二硫酸钠
线性分子式:
Na2S2O8
CAS号:
7775-27-1
分子量:
238.10
EC 号:
231-892-1
MDL编号:
MFCD00003501
PubChem化学物质编号:
329752185
NACRES:
NA.21

等级

reagent grade

质量水平

200

检测方案

≥98%

形式

powder, crystals or granules

reaction suitability

reagent type: oxidant

SMILES string

[Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O

InChI

1S/2Na.H2O8S2/c;;1-9(2,3)7-8-10(4,5)6/h;;(H,1,2,3)(H,4,5,6)/q2*+1;/p-2

InChI key

CHQMHPLRPQMAMX-UHFFFAOYSA-L

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相关类别

一般描述

Sodium persulfate, also known as Sodium peroxodisulfate is an inorganic compound and is a water-soluble strong oxidizing agent, that is stable and easy to handle. It is commonly used as an oxidant in organic synthesis reactions such as transition-metal-catalyzed or metal-free reactions. Additionally, it is used as a polymerization initiator and in the synthesis of sulfate radical anions through heat-activated decomposition.

应用

过硫酸钠可用作氧化剂：
  • 2-炔基苯并腈与芳基亚磺酸钠的自由基环化级联反应，以合成磺化茚酮。
  • 通过二氧化硅负载的氯化铝催化 Baeyer-Villiger 氧化将环和无环酮转化为内酯或酯。
还可用作苯乙烯聚合的引发剂，以合成聚苯乙烯。

警示用语：

Danger

危险分类

Acute Tox. 4 Oral - Ox. Sol. 3 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

靶器官

Respiratory system

储存分类代码

5.1B - Oxidizing hazardous materials

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

危险化学品

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PCE oxidation by sodium persulfate in the presence of solids
Jed C, et al.
Environmental Science & Technology, 44, 9445-9450 (2010)
Esther Eljarrat-Binstock et al.
Investigative ophthalmology & visual science, 45(8), 2543-2548 (2004-07-28)
To assess the corneal iontophoretic delivery of gentamicin by drug-loaded hydrogel probe, and to determine the resultant ocular disposition and elimination of the drug from the cornea and anterior chamber. Corneal iontophoresis of gentamicin sulfate was studied in healthy white
Olha S Furman et al.
Environmental science & technology, 44(16), 6423-6428 (2010-08-14)
Base is the most commonly used activator of persulfate for the treatment of contaminated groundwater by in situ chemical oxidation (ISCO). A mechanism for the base activation of persulfate is proposed involving the base-catalyzed hydrolysis of persulfate to hydroperoxide anion
Yu-Chieh Chou et al.
Journal of hazardous materials, 246-247, 79-86 (2013-01-05)
Microwave oxidation process (MOP) was evaluated for treatment of landfill leachate. The experimental parameters include pH, temperature, oxidant doses, microwave power setting, and irradiation time. The study explored the microwave-specific effects of the MOP. The contributions of pure thermal, persulfate
José Fenoll et al.
Journal of hazardous materials, 244-245, 370-379 (2012-12-29)
The photocatalytic degradation of sixteen substituted phenylurea herbicides (PUHs) in pure water has been studied using zinc oxide (ZnO) and titanium dioxide (TiO(2)) as photocatalyst under artificial light irradiation. Photocatalytic experiments showed that the addition of these chalcogenide oxides in
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