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经验公式(希尔记法):
AlCl3 · 6H2O
化学文摘社编号:
分子量:
241.43
NACRES:
NA.55
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-208-1
MDL number:
Assay:
99%
Form:
crystalline solid
crystals or chunks
crystals or chunks
产品名称
氯化铝 六水合物, ReagentPlus®, 99%
InChI key
JGDITNMASUZKPW-UHFFFAOYSA-K
InChI
1S/Al.3ClH.6H2O/h;3*1H;6*1H2/q+3;;;;;;;;;/p-3
SMILES string
Cl[Al](Cl)Cl.O.O.O.O.O.O
vapor pressure
1 mmHg ( 100 °C)
product line
ReagentPlus®
assay
99%
form
crystalline solid
crystals or chunks
reaction suitability
reagent type: catalyst
core: aluminum
pH
2.5-3.5 (20 °C)
Quality Level
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Application
氯化铝六水合物用作催化剂:
- 用于醇或酚和3,4-二氢-2H-吡喃(DHP)合成对应的THP(四氢吡喃)醚。
- 用于乙酰丙酸和乙醇直接酯化生产乙酰丙酸乙酯。
- 用于由酮和醛合成gem-二氢过氧化物。
General description
氯化铝六水合物是一种不易燃的化合物,广泛用作有机合成中的催化剂。除极易溶于水外,还溶于乙醇、乙醚、甘油、丙二醇和乙腈。它有很多用途,包括原油提炼、生产除臭剂和止汗产品、织物染色、纺织品整理。
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B - STOT RE 1
target_organs
Lungs
supp_hazards
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
危险化学品
此项目有
[Axillary hyperhydrosis. Local treatment with 25% aluminum chloride hexahydrate in absolute alcohol].
F Brandrup et al.
Ugeskrift for laeger, 140(35), 2106-2109 (1978-08-28)
Mark Baranov et al.
Inorganic chemistry, 58(13), 8877-8883 (2019-06-30)
While sophisticated computational methods can predict 31P NMR spectra of phosphorus atoms encapsulated within Keggin-derived heteropoly tungstate and molybdate cluster anions, calculated and experimental chemical shift values typically deviate considerably from one another. Motivated by the observation that experimentally determined
Aluminium (III) chloride hexahydrate: an efficient and versatile reagent in organic synthesis.
Sarma SD, et al.
ARKIVOC (Gainesville, FL, United States), 1, 243-263 (2013)
C L Goh
International journal of dermatology, 29(5), 368-370 (1990-06-01)
The efficacy of topical aluminium chloride hexahydrate 20% W/W ethanol (ACH) in the treatment symptomatic palmar hyperhidrosis was studied in 12 patients. A half-sided control single blind (assessor blind) study was done. Patients applied ACH on one palm daily for
A neutron and X-ray diffraction investigation of aluminum chloride hexahydrate.
Buchanan DR and Harris PM.
Acta Crystallographica Section B, Structural Science, 24(7), 954-960 (1968)
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