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259705

甲酸甲酯

Name: 甲酸甲酯
Brand: SIGALD

spectrophotometric grade, ≥98%

别名:

蚁酸甲酯

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关于此项目

线性分子式:

HCO₂CH₃

化学文摘社编号:

107-31-3

分子量:

60.05

UNSPSC Code:

12352108

NACRES:

NA.21

PubChem Substance ID:

329752838

EC Number:

203-481-7

Beilstein/REAXYS Number:

1734623

MDL number:

MFCD00003291

Assay:

≥98%

Grade:

spectrophotometric grade

Technique(s):

UV/Vis spectroscopy: suitable

Bp:

32-34 °C (lit.)

Vapor pressure:

32.81 psi ( 55 °C), 9.21 psi ( 20 °C)

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属性

grade

spectrophotometric grade

Quality Level

100

vapor density

2.1 (vs air)

vapor pressure

32.81 psi ( 55 °C), 9.21 psi ( 20 °C)

assay

≥98%

form

liquid

autoignition temp.

842 °F

expl. lim.

23 %

technique(s)

UV/Vis spectroscopy: suitable

impurities

<0.05% water

evapn. residue

<0.0005%

refractive index

n20/D 1.343 (lit.)

pH

4.0-5.0 (20 °C, 200 g/L)

bp

32-34 °C (lit.)

mp

−100 °C (lit.)

density

0.974 g/mL at 20 °C (lit.)

λ

H₂O reference

UV absorption

λ: 259 nm A_max: 1.00, λ: 260 nm A_max: 0.70, λ: 265 nm A_max: 0.20, λ: 270 nm A_max: 0.04, λ: 310-400 nm A_max: 0.1

SMILES string

[H]C(=O)OC

InChI

1S/C2H4O2/c1-4-2-3/h2H,1H3

InChI key

TZIHFWKZFHZASV-UHFFFAOYSA-N

说明

General description

Methyl formate (MF) is one of the most significant intermediates in C₁ chemistry. MF has been used to produce methanamide, N, N-dimethylformamide, dimethyl carbonate, methyl glycolate, acetic acid, ethylene glycol, methyl methacrylate, and high-purity CO. Additionally, MF can be used as a solvent for nitrocellulose and cellulose acetate.

Application

Bifunctionality of Re Supported on TiO(2) in Driving Methanol Formation in Low-Temperature CO(2) Hydrogenation.: This article explores the catalytic roles of methyl formate in methanol production from CO2 hydrogenation, providing a pathway for sustainable chemical synthesis (Urakawa A et al., 2023).

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pictograms

GHS02,GHS06,GHS08

signalword

Danger

hcodes

H224,H301 + H311 + H331,H319,H335,H370

pcodes

P210 - P280 - P301 + P310 + P330 - P302 + P352 + P312 - P304 + P340 + P311 - P403 + P233

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 1 - STOT SE 1 - STOT SE 3

target_organs

Respiratory system

存储类别

3 - Flammable liquids

wgk

WGK 2

flash_point_f

-2.2 °F - closed cup

flash_point_c

-19 °C - closed cup

法规信息

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分析证书(COA)

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Methyl N-Phenyl Carbamate Synthesis from Aniline and Methyl Formate: Carbon Recycling to Chemical Products.

Yalfani MS, et al.

ChemSusChem, 8(3), 443-447 (2015)

Sequential photo-oxidation of methanol to methyl formate on TiO2(110).

Katherine R Phillips et al.

Journal of the American Chemical Society, 135(2), 574-577 (2012-12-28)

Methyl formate is produced from the photo-oxidation of methanol on preoxidized TiO(2)(110). We demonstrate that two consecutive photo-oxidation steps lead to methyl formate using mass spectrometry and scanning tunneling microscopy. The first step in methanol oxidation is formation of methoxy

Barriers to rotation adjacent to double bonds. 3. The carbon-oxygen barrier in formic acid, methyl formate, acetic acid, and methyl acetate. The origin of ester and amide resonance.

Wiberg KB and Laidig KE.

Journal of the American Chemical Society, 109(20), 5935-5943 (1987)

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全球贸易项目编号

货号	GTIN
259705-2L	04061826075425
259705-1L	04061837678066