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线性分子式:
ZrOCl2 · 8H2O
化学文摘社编号:
分子量:
322.25
UNSPSC Code:
12352112
PubChem Substance ID:
EC Number:
231-717-9
MDL number:
Assay:
≥99.5%
Form:
liquid
InChI key
IZYKRMGFEBSOSO-UHFFFAOYSA-L
InChI
1S/2ClH.8H2O.O.Zr/h2*1H;8*1H2;;/q;;;;;;;;;;;+2/p-2
SMILES string
O.O.O.O.O.O.O.O.Cl[Zr](Cl)=O
grade
puriss. p.a.
assay
≥99.5%
form
liquid
impurities
≤0.001% heavy metals (as Pb)
anion traces
sulfate (SO42-): ≤50 mg/kg
cation traces
Fe: ≤10 mg/kg, Ti: ≤50 mg/kg
suitability
passes test for suitability as micro reagent
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General description
Crystal structure studies of zirconium(IV) oxychloride octahydrate (zirconyl chloride octahydrate, zirconium(IV) oxide chloride) confirms the presence of [Zr4(OH)8(H2O)16]8+ tetranuclear complex in its crystals. Crystal structure has been evaluated by least-squares method with new three-dimensional data.
Application
Zirconium(IV) oxychloride octahydrate (Zirconyl chloride octahydrate, Zirconium(IV) oxide chloride, ZrOCl2.8H2O) may be used for the preparation of 2-substituted benzothiazoles. ZrOCl2.8H2O dissolved in ethanol may be employed as a standard green solvent during the synthesis of quinoxaline derivatives.
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8B - Non-combustible corrosive hazardous materials
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
此项目有
A new catalytic method for eco-friendly synthesis of quinoxalines by zirconium (IV) oxide chloride octahydrate under mild conditions.
Jafarpour M, et al.
Letters in Organic Chemistry, 8(3), 202-209 (2011)
Zirconium (IV) oxide chloride and anhydrous copper (II) sulfate mediated synthesis of 2-substituted benzothiazoles.
Moghaddam FM, et al.
Heteroatom Chem., 17(2), 136-141 (2006)
Refinement of the crystal structure of zirconyl chloride octahydrate.
Mak TCW.
Canadian Journal of Chemistry, 46(22), 3491-3497 (1968)
D R Mulinari et al.
Carbohydrate research, 345(13), 1865-1871 (2010-07-06)
Surface modification of natural fibers has been made using different methods. In this paper, cellulose fibers from sugarcane bagasse were bleached and modified by zirconium oxychloride in situ. The chemically modified cellulose fibers were compared to those of bleached ones.
S Ghosh et al.
Toxicology letters, 55(2), 195-201 (1991-02-01)
Zirconium oxychloride was administered as a single oral dose to laboratory-bred Swiss albino mice corresponding to 1/2, 1/6 and 1/20 of the LD50 values. Bone marrow cells were screened after 6, 12 and 24h for chromosomal aberrations following an air-drying-Giemsa
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