表单
liquid
反应适用性
reagent type: catalyst
core: titanium
浓度
0.95-1.10 M NaOH (titration)
1.0 M in toluene
密度
0.964 g/mL at 25 °C
SMILES字符串
Cl[Ti](Cl)(Cl)Cl
InChI
1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4
InChI key
XJDNKRIXUMDJCW-UHFFFAOYSA-J
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一般描述
Titanium(IV) chloride participates in the Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone.
应用
TiCl4 can be used as a precursor for the synthesis of nanosized titaniuim dioxide.
警示用语：
Danger
危险分类
Acute Tox. 2 Inhalation - Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3
靶器官
Central nervous system, Respiratory system
补充剂危害
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
46.4 °F - closed cup
闪点(°C)
8 °C - closed cup
法规信息
新产品
此项目有
Titanium(IV) chloride and the amine-promoted baylis-hillman reaction
Shi et al.
Organic letters, 2(23), 3755-3755 (2000-11-14)
Precipitation of nanosized titanium dioxide from aqueous titanium (IV) chloride solutions by neutralization with MgO.
Li Y and Demopoulos GP.
Hydrometallurgy, 90(1), 26-33 (2008)
Denton, S.M. Wood, A.
Synlett, 55-55 (1999)
Soji Shimizu et al.
Chemical communications (Cambridge, England), 49(16), 1621-1623 (2013-01-23)
Pyrrolopyrrole aza-BODIPY analogues were synthesized from diketopyrrolopyrrole and heteroaromatic amines in the presence of titanium tetrachloride. These novel compounds exhibit intense absorption in the visible region and strong emission with high fluorescence quantum yields greater than 0.8.
Kun Wang et al.
The oncologist, 20(3), 263-269 (2015-02-07)
The TERT promoter and FGFR3 gene mutations are two of the most common genetic events in urothelial bladder cancer (UBC), and these mutation assays in patient urine have been shown to be promising biomarkers for UBC diagnosis and surveillance. These
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