InChI
1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4
SMILES string
Cl[Ti](Cl)(Cl)Cl
InChI key
XJDNKRIXUMDJCW-UHFFFAOYSA-J
form
liquid
reaction suitability
reagent type: catalyst
core: titanium
concentration
0.95-1.10 M NaOH (titration), 1.0 M in toluene
density
0.964 g/mL at 25 °C
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General description
Titanium(IV) chloride participates in the Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone.
Application
TiCl4 can be used as a precursor for the synthesis of nanosized titaniuim dioxide.
signalword
Danger
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
flash_point_f
46.4 °F - closed cup
flash_point_c
8 °C - closed cup
Hazard Classifications
Acute Tox. 2 Inhalation - Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 Inhalation - STOT SE 3
法规信息
新产品
此项目有
Precipitation of nanosized titanium dioxide from aqueous titanium (IV) chloride solutions by neutralization with MgO.
Li Y and Demopoulos GP.
Hydrometallurgy, 90(1), 26-33 (2008)
Titanium(IV) chloride and the amine-promoted baylis-hillman reaction
Shi et al.
Organic letters, 2(23), 3755-3755 (2000-11-14)
Denton, S.M. Wood, A.
Synlett, 55-55 (1999)
Bratindranath Mukherjee et al.
Nanoscale, 5(1), 269-274 (2012-11-20)
The surface treatment of an anodized TiO(2) nanotube (T_NT) is very desirable for enhancing its photoelectrochemical properties and often is a prerequisite to deposition of any overlying layer for photoactivity efficiency improvement. This study provides a comparative analysis of the
Yang Chen et al.
ChemSusChem, 4(10), 1498-1503 (2011-09-29)
Mesoporous TiO₂ beads with diameters of 320±50, 550±50, and 830±40 nm, comprising interconnected and densely packed TiO₂ nanocrystals, were used as working electrodes for dye-sensitized solar cells (DSCs). These electrodes possess high surface areas and superior light-scattering properties, which are ideal
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