产品名称
四氯化钛(IV) 溶液, 1.0 M in toluene
InChI
1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4
SMILES string
Cl[Ti](Cl)(Cl)Cl
InChI key
XJDNKRIXUMDJCW-UHFFFAOYSA-J
form
liquid
reaction suitability
reagent type: catalyst
core: titanium
concentration
0.95-1.10 M NaOH (titration)
1.0 M in toluene
density
0.964 g/mL at 25 °C
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Application
TiCl4 can be used as a precursor for the synthesis of nanosized titaniuim dioxide.
General description
Titanium(IV) chloride participates in the Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone.
signalword
Danger
Hazard Classifications
Acute Tox. 2 Inhalation - Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
46.4 °F - closed cup
flash_point_c
8 °C - closed cup
法规信息
新产品
此项目有
Titanium(IV) chloride and the amine-promoted baylis-hillman reaction
Shi et al.
Organic letters, 2(23), 3755-3755 (2000-11-14)
Precipitation of nanosized titanium dioxide from aqueous titanium (IV) chloride solutions by neutralization with MgO.
Li Y and Demopoulos GP.
Hydrometallurgy, 90(1), 26-33 (2008)
Denton, S.M. Wood, A.
Synlett, 55-55 (1999)
Charles Dylan Turner et al.
Organic letters, 14(18), 4970-4973 (2012-09-08)
The Ti(IV)-catalyzed Ugi condensation of α-amino acids with electron-rich aromatic aldehydes performs adequately even with sterically demanding α-amino carboxylate salts. The reaction occurs diastereoselectively, in some cases with virtually complete diastereoselectivity. A stereochemical rationale for the reaction is proposed.
Soji Shimizu et al.
Chemical communications (Cambridge, England), 49(16), 1621-1623 (2013-01-23)
Pyrrolopyrrole aza-BODIPY analogues were synthesized from diketopyrrolopyrrole and heteroaromatic amines in the presence of titanium tetrachloride. These novel compounds exhibit intense absorption in the visible region and strong emission with high fluorescence quantum yields greater than 0.8.
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