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Merck
CN

398276

二异丙基醚

contains either BHT or hydroquinone as stabilizer, ACS reagent, ≥99.0%

别名:

异丙醚

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线性分子式:
(CH3)2CHOCH(CH3)2
化学文摘社编号:
分子量:
102.17
UNSPSC Code:
12191502
NACRES:
NA.07
PubChem Substance ID:
EC Number:
203-560-6
Beilstein/REAXYS Number:
1731256
MDL number:
Assay:
≥99.0%
Grade:
ACS reagent
Bp:
68-69 °C (lit.)
Vapor pressure:
120 mmHg ( 20 °C)
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InChI key

ZAFNJMIOTHYJRJ-UHFFFAOYSA-N

InChI

1S/C6H14O/c1-5(2)7-6(3)4/h5-6H,1-4H3

SMILES string

CC(C)OC(C)C

grade

ACS reagent

vapor density

3.5 (vs air)

vapor pressure

120 mmHg ( 20 °C)

assay

≥99.0%

form

liquid

autoignition temp.

827 °F

contains

either BHT or hydroquinone as stabilizer

expl. lim.

1-21 %, 100 °F

dilution

(for analytical testing)

impurities

≤0.0007 meq/g Titr. acid, ≤0.05% Peroxide (as C6H14O2)

evapn. residue

≤0.01%

color

APHA: ≤25

Quality Level

bp

68-69 °C (lit.)

mp

−85 °C (lit.)

density

0.725 g/mL at 25 °C (lit.)

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General description

Diisopropyl ether (DIPE) is branched ether. It is a peroxide forming solvent. This process is catalyzed by heat, light and oxygen. For such solvents small amount of stabilizers like BHT (butylated hydroxytoluene) or hydroquinone is added which removes the free radicals that form peroxides. DIPE has been proposed as a potential alternative oxygenated fuel additive. Several methods have been proposed for its synthesis using acetone as starting material. The molecular structure and conformation has been studied using gas-phase electron diffusion. Its potential carcinogenicity has been studied in Sprague-Dawley rats.
Our premium ACS solvents are ideal for routine chemical synthesis, drying, purification, and critical labware cleaning. They meet or exceed the rigorous standards of the American Chemical Society (ACS), ensuring high-quality results for your research needs.

Premium ACS Solvents: Our solvents meet or exceed the stringent standards set by the American Chemical Society, ensuring high quality and reliability for your laboratory applications.

Replicable and Publishable Results: Designed for consistency, our solvents deliver results that can be reliably reproduced, making them ideal for research that requires publication.

Versatile Applications: Suitable for routine chemical synthesis, drying, purification, and critical labware cleaning, our solvents cater to a wide range of research needs in the laboratory.

Application

Diisopropyl ether may be used as a solvent in the following processes:
  • Resolution of secondary alcohols.
  • Enantioselective acylation of 1-phenethylamine.
  • Synthesis of aliphatic and aromatic cyanohydrins.

pictograms

FlameExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Flam. Liq. 2 - STOT SE 3

target_organs

Central nervous system

supp_hazards

存储类别

3 - Flammable liquids

wgk

WGK 1

flash_point_f

-20.2 °F - closed cup

flash_point_c

-29 °C - closed cup

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Resolution of secondary alcohols using lipase in diisopropyl ether.
Bevinakatti HS, et al.
The Journal of Organic Chemistry, 54(10), 2453-2455 (1989)
Diisopropyl ether one-step generation from acetone-rich feedstocks.
Taylor RJ, et al.
Catalysis Letters, 68(1-2), 1-5 (2000)
Diisopropyl ether syntheses from crude acetone.
Knifton JF and D PSE.
Catalysis Letters, 57(4), 193-197 (1999)
Cross-linked enzyme aggregates (CLEAs): stable and recyclable biocatalysts.
Sheldon RA.
Biochemical Society Transactions, 35(6) (2007)
Molecular structure and conformation of diisopropyl ether: a gas electron diffraction investigation.
Takeuchi H, et al.
The Journal of Physical Chemistry, 91(5), 1015-1019 (1987)

实验方案

A guide to create solvent systems used for the thin-layer chromatography assay of Novabiochem products.

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