402990
一氯化碘
ACS reagent, 1.10±0.1 I/Cl ratio basis
别名:
氯化碘
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关于此项目
线性分子式:
ICl
化学文摘社编号:
分子量:
162.36
NACRES:
NB.24
PubChem Substance ID:
UNSPSC Code:
12352300
EC Number:
232-236-7
MDL number:
Grade:
ACS reagent
Form:
solid or liquid
Solubility:
acetic acid: soluble(lit.)
acetone: soluble(lit.)
alcohol: soluble(lit.)
carbon disulfide: soluble(lit.)
acetone: soluble(lit.)
alcohol: soluble(lit.)
carbon disulfide: soluble(lit.)
产品名称
一氯化碘, ACS reagent, 1.10±0.1 I/Cl ratio basis
InChI key
QZRGKCOWNLSUDK-UHFFFAOYSA-N
InChI
1S/ClI/c1-2
SMILES string
ClI
grade
ACS reagent
form
solid or liquid
impurities
≤0.005% insolubles
bp
97.4 °C (lit.)
solubility
acetic acid: soluble(lit.)
acetone: soluble(lit.)
alcohol: soluble(lit.)
carbon disulfide: soluble(lit.)
density
3.24 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
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Application
Iodine monochloride (ICl) may be employed for the halogenation of methoxy and dimethoxybenzenes. It may be used for the synthesis of flavones.
Iodine monochloride may be used in the synthesis of the following:
- 2-(4-haloisoquinolin-1-yl)ethanol derivatives
- 5-iodosalicylaldehydes
- 5-aryl-6-iodo-8-phenylpyrazolo[1,5-c]-1,2,4-triazolo[4,3-a]pyrimidines
- (±)-1-cyclohexyl-4-iodo-3-methoxybutan-1-ol
- (±)-4-Iodo-3-methoxy-1-phenylbutan-1-ol
General description
Iodine monochloride is an interhalogen compound. It forms various complexes with ethyl, isopropyl and t-butylbenzenes. Equilibrium constants for the formation of these complexes have been evaluated. It affords electrically conducting solution on dissolution in polar solvents. Its reaction with thymidine, 3-mono- and 3,3′,5′-trialkylsubstitued thymidine showed that it helps in deglycosylation, anomerization and isomerization of thymidine.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
危险化学品
此项目有
Brisbois RG, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2013)
Synthesis and Electrophilic Substitutions of Novel Pyrazolo [1, 5-c]-1, 2, 4-triazolo [4, 3-a] pyrimidines.
Atta KFM.
Molecules (Basel), 16(8), 7081-7096 (2011)
Eric Stefan et al.
Tetrahedron, 69(36), 7706-7712 (2013-09-24)
Ether transfer methodology is capable of stereoselectively generating 1,3-diol mono- and diethers in good yield. Surprisingly, allylic and benzylic substrates provide none of the desired products when exposed to previously optimized conditions of iodine monochloride. Herein, second-generation activation conditions for
Synthesis of Luminescent Ethynyl-Extended Regioisomers of Borate Complexes Based on 2-(2'-Hydroxyphenyl) benzoxazole.
23 Massue J, et al.
Chemistry (Weinheim An Der Bergstrasse, Germany), 19(17), 5375-5386 (2013)
Eagleson M.
Concise Encyclopedia Chemistry, 477-477 (1994)
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