等级
ACS reagent
质量水平
表单
solid or liquid
杂质
≤0.005% insolubles
沸点
97.4 °C (lit.)
溶解性
acetic acid: soluble(lit.)
acetone: soluble(lit.)
alcohol: soluble(lit.)
carbon disulfide: soluble(lit.)
密度
3.24 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
ClI
InChI
1S/ClI/c1-2
InChI key
QZRGKCOWNLSUDK-UHFFFAOYSA-N
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一般描述
Iodine monochloride is an interhalogen compound. It forms various complexes with ethyl, isopropyl and t-butylbenzenes. Equilibrium constants for the formation of these complexes have been evaluated. It affords electrically conducting solution on dissolution in polar solvents. Its reaction with thymidine, 3-mono- and 3,3′,5′-trialkylsubstitued thymidine showed that it helps in deglycosylation, anomerization and isomerization of thymidine.
应用
Iodine monochloride (ICl) may be employed for the halogenation of methoxy and dimethoxybenzenes. It may be used for the synthesis of flavones.
Iodine monochloride may be used in the synthesis of the following:
- 2-(4-haloisoquinolin-1-yl)ethanol derivatives
- 5-iodosalicylaldehydes
- 5-aryl-6-iodo-8-phenylpyrazolo[1,5-c]-1,2,4-triazolo[4,3-a]pyrimidines
- (±)-1-cyclohexyl-4-iodo-3-methoxybutan-1-ol
- (±)-4-Iodo-3-methoxy-1-phenylbutan-1-ol
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
靶器官
Respiratory system
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
危险化学品
此项目有
Three-Component Reactions of 2-Alkynylbenzaldoximes and α, β-Unsaturated Carbonyl Compounds with Bromine or Iodine Monochloride.
Ye S, et al.
Advanced Synthesis & Catalysis, 352(10), 1746-1751 (2010)
Eagleson M.
Concise Encyclopedia Chemistry, 477-477 (1994)
Brisbois RG, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2013)
Eric Stefan et al.
Tetrahedron, 69(36), 7706-7712 (2013-09-24)
Ether transfer methodology is capable of stereoselectively generating 1,3-diol mono- and diethers in good yield. Surprisingly, allylic and benzylic substrates provide none of the desired products when exposed to previously optimized conditions of iodine monochloride. Herein, second-generation activation conditions for
Synthesis and Electrophilic Substitutions of Novel Pyrazolo [1, 5-c]-1, 2, 4-triazolo [4, 3-a] pyrimidines.
Atta KFM.
Molecules (Basel), 16(8), 7081-7096 (2011)
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