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经验公式(希尔记法):
CS2
化学文摘社编号:
分子量:
76.14
UNSPSC Code:
12352100
NACRES:
NA.21
PubChem Substance ID:
EC Number:
200-843-6
Beilstein/REAXYS Number:
1098293
MDL number:
Assay:
≥99.9%
Bp:
46 °C (lit.)
Vapor pressure:
5.83 psi
InChI key
QGJOPFRUJISHPQ-UHFFFAOYSA-N
InChI
1S/CS2/c2-1-3
SMILES string
S=C=S
vapor density
2.67 (vs air)
vapor pressure
5.83 psi
product line
ReagentPlus®
assay
≥99.9%
form
liquid
autoignition temp.
212 °F
purified by
redistillation
expl. lim.
50 %
dilution
(for general lab use)
impurities
≤0.03% (water), ≤1.5 ppm hydrogen sulfide, ≤2.5 ppm sulfur dioxide, <100 ppb benzene (No single impurity > 100 ppb, measured as benzene), <500 ppb total hydrocarbon content
color
APHA: ≤10
Quality Level
bp
46 °C (lit.)
mp
−112-−111 °C (lit.)
solubility
alcohol: miscible(lit.), benzene: miscible(lit.)
density
1.266 g/mL at 25 °C (lit.)
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General description
Carbon disulfide is a toxic, highly volatile, flammable liquid with low ignition temperature. It can be synthesized by reacting hydrocarbon gas with sulfur. It is an important raw material for preparing viscose rayon and cellophane film. It shows fat solvent property. CS2 in water assists the peptide bond formation in amino acids.
Application
Carbon disulfide may be used in the xanthogenation of cellulose and in the synthesis of poly(ethylene trithiocarbonate).
Suitable for industrial hygiene analysis
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
Hazard Classifications
Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1
target_organs
Peripheral nervous system,Central nervous system,Cardio-vascular system,Eyes
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
-22.0 °F - closed cup
flash_point_c
-30 °C - closed cup
法规信息
新产品
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Luke J Leman et al.
Astrobiology, 15(9), 709-716 (2015-08-27)
Demonstrating plausible nonenzymatic polymerization mechanisms for prebiotic monomers represents a fundamental goal in prebiotic chemistry. While a great deal is now known about the potentially prebiotic synthesis of amino acids, our understanding of abiogenic polymerization processes to form polypeptides is
Copolymerization of ethylene sulfide and carbon disulfide.
Soga K, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 14(3), 677-684 (1976)
Carbon Disulfide.
Smith DE and Timmerman RW.
Kirk-Othmer Encyclopedia of Chemical Technology (2003)
Xanthogenation of lignocarbohydrates by carbon disulfide.
Efanov MV and Pershina LA.
Chemistry of Natural Compounds, 38(1), 90-94 (2002)
Margherita Maiuri et al.
Physical chemistry chemical physics : PCCP, 14(18), 6312-6319 (2012-02-15)
In carotenoids internal conversion between the allowed (S(2)) and forbidden (S(1)) excited states occurs on a sub-picosecond timescale; the involvement of an intermediate excited state(s) (S(x)) mediating the process is controversial. Here we use high time resolution (sub-20 fs) broadband
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