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Merck
CN

61168

氯化亚铜

puriss. p.a., ACS reagent, ≥97.0% (RT)

别名:

一氯化铜

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关于此项目

线性分子式:
CuCl
化学文摘社编号:
分子量:
99.00
NACRES:
NB.24
PubChem Substance ID:
UNSPSC Code:
12352300
EC Number:
231-842-9
MDL number:
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InChI key

OXBLHERUFWYNTN-UHFFFAOYSA-M

InChI

1S/ClH.Cu/h1H;/q;+1/p-1

SMILES string

Cl[Cu]

grade

ACS reagent, puriss. p.a.

vapor pressure

1.3 mmHg ( 546 °C)

assay

≥97.0% (RT)

form

powder

reaction suitability

reagent type: catalyst
core: copper

impurities

≤0.02% insoluble in acid

pH

5 (20 °C, 50 g/L)

bp

1490 °C (lit.)

mp

430 °C (lit.)

solubility

dimethyl sulfide: partially soluble(lit.), water: insoluble(lit.)

anion traces

sulfate (SO42-): ≤750 mg/kg

cation traces

Ca: ≤10 mg/kg, Cd: ≤5 mg/kg, Co: ≤5 mg/kg, Cr: ≤50 mg/kg, Fe: ≤100 mg/kg, K: ≤50 mg/kg, Mg: ≤5 mg/kg, Mn: ≤5 mg/kg, Na: ≤500 mg/kg, Ni: ≤5 mg/kg, Pb: ≤200 mg/kg, Zn: ≤5 mg/kg

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Application

作为自由基反应(如 α,β-不饱和酮的锡氢化作用)的引发剂表现出独特的性质。
Copper(I) chloride (Cuprous chloride) may be used in the stereospecific synthesis of cyclic conjugated dienes. It may be employed as a reactant to investigate the stability of copper chloride complexes in hydrothermal solutions.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Copper (I) Chloride.
Bertz SH, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2007)
Experimental study of copper (I) chloride complexing in hydrothermal solutions at 40 to 300 ?C and saturated water vapor pressure.
Xiao Z, et al.
Geochimica et Cosmochimica Acta, 62(17), 2949-2964 (1998)
Copper (I) chloride-mediated intramolecular coupling of vinyltrimethylstannane and vinyl halide functions.
Piers E and Wong T.
The Journal of Organic Chemistry, 58(14), 3609-3610 (1993)
Xiaoliang Xu et al.
Organic letters, 12(5), 897-899 (2010-02-04)
Promoted by CuCl/CCl(4), a variety of sulfonyl azides and tertiary amines were successfully coupled to give sulfonyl amidine derivatives in good to excellent yields. A possible mechanism for this reaction is discussed.
Takayoshi Arai et al.
The Journal of organic chemistry, 73(13), 4903-4906 (2008-06-03)
A catalytic asymmetric Henry reaction has been developed with use of a sulfonyldiamine-CuCl complex as a catalyst. A series of new binaphthyl-containing sulfonyldiamine ligands (2a-h) were readily synthesized in two steps starting from commercially available chiral 1,2-diamines. The (R,R)-diamine-(R)-binaphthyl ligand

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