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Merck
CN

62531

氢氧化锂 一水合物

puriss. p.a., ≥99.0% (T)

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线性分子式:
LiOH · H2O
化学文摘社编号:
分子量:
41.96
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
215-183-4
MDL number:
Assay:
≥99.0% (T)
Form:
powder or crystals
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InChI key

GLXDVVHUTZTUQK-UHFFFAOYSA-M

InChI

1S/Li.2H2O/h;2*1H2/q+1;;/p-1

SMILES string

[Li+].O.[OH-]

grade

puriss. p.a.

assay

≥99.0% (T)

form

powder or crystals

pH

12 (0.4 g/L)

anion traces

chloride (Cl-): ≤50 mg/kg, lithium carbonate (Li2CO3): ≤1%, sulfate (SO42-): ≤100 mg/kg

cation traces

Ag: ≤5 mg/kg, Al: ≤20 mg/kg, Ba: ≤5 mg/kg, Bi: ≤5 mg/kg, Ca: ≤50 mg/kg, Cd: ≤5 mg/kg, Co: ≤5 mg/kg, Cr: ≤5 mg/kg, Cu: ≤5 mg/kg, Fe: ≤5 mg/kg, K: ≤200 mg/kg, Mg: ≤5 mg/kg, Mn: ≤5 mg/kg, Mo: ≤5 mg/kg, Na: ≤50 mg/kg, Ni: ≤5 mg/kg, Pb: ≤5 mg/kg, Sr: ≤5 mg/kg, Tl: ≤5 mg/kg, Zn: ≤5 mg/kg

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General description

Lithium hydroxide monohydrate is a hydrate of alkali metal hydroxide. Its IR spectral analysis has been reported. A refinement of its crystal structure has been described. Its crystals belong to the monoclinic crystal system having space group C2/m. It can be prepared by reacting Li metal with H2O, followed by the evaporation of the aqueous solution. It can be also be obtained from the basic aqueous solution of LiOH, via crystallization.

Application

Lithium hydroxide monohydrate (LiOH.H2O) may be employed as a catalyst for the melt transesterification of diphenyl carbonate and bisphenol A. Kinetics of this transesterification reaction have been investigated.

Other Notes

用于分解氧化物和硅酸盐的试剂

pictograms

CorrosionExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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历史批次信息供参考:

分析证书(COA)

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访问文档库

Z. Sulcek et al.
Methods of Decomposition in Inorganic Analysis (1989)
R. Bock
Aufschlussmethoden der anorg. & org. Chemie (1972)
Hydrogen bonding. VI. Structural and infrared spectral analysis of lithium hydroxide monohydrate and cesium and rubidium hydroxide hydrates.
Gennick I and Harmon KM.
Inorganic Chemistry, 14(9), 2214-2219 (1975)
Refinement of the crystal structure of lithium hydroxide monohydrate.
Alcock NW.
Acta Crystallographica Section B, Structural Science, Crystal Engineering and Materials, 27(8), 1682-1683 (1971)
Kinetics of melt transesterification of diphenyl carbonate and bisphenol A to polycarbonate with lithium hydroxide monohydrate catalyst.
Kim Y, et al.
Industrial & Engineering Chemistry Research, 31(9), 2118-2127 (1992)

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