85140
醋酸银
purum p.a., ≥99.0% (T)
别名:
醋酸 银盐
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线性分子式:
CH3COOAg
化学文摘社编号:
分子量:
166.91
UNSPSC Code:
12352300
NACRES:
NA.21
PubChem Substance ID:
EC Number:
209-254-9
Beilstein/REAXYS Number:
3595636
MDL number:
InChI key
CQLFBEKRDQMJLZ-UHFFFAOYSA-M
InChI
1S/C2H4O2.Ag/c1-2(3)4;/h1H3,(H,3,4);/q;+1/p-1
SMILES string
CC(O[Ag])=O
grade
purum p.a.
assay
≥99.0% (T)
form
powder
anion traces
sulfate (SO42-): ≤500 mg/kg
cation traces
Ca: ≤50 mg/kg, Cd: ≤50 mg/kg, Co: ≤50 mg/kg, Cu: ≤50 mg/kg, Fe: ≤50 mg/kg, K: ≤150 mg/kg, Na: ≤100 mg/kg, Ni: ≤50 mg/kg, Pb: ≤50 mg/kg, Zn: ≤50 mg/kg
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General description
Reaction of silver carbonate with acetic acid at 45-60°C has been reported to afford silver acetate. It participates in the conversion of carboxylic acid chlorides to amides, via aminolysis.
Application
用于高反射性、导电性银聚合物膜的新型制备方法。亦可用于有效催化异氰基乙酸酯与多种烯烃的环加成反应。
Silver acetate may be used in the synthesis of α-cis glycol and β-cis glycol. It may be used as a catalyst in the synthesis of Δ1- or Δ2-pyrrolines.
signalword
Warning
hcodes
Hazard Classifications
Aquatic Acute 1 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Silver acetate catalysed cycloadditions of isocyanoacetates.
Grigg R, et al.
Tetrahedron, 55(7), 2025-2044 (1999)
Study of thermal decomposition of silver acetate.
Logvinenko V, et al.
Journal of Thermal Analysis and Calorimetry, 90(3), 813-816 (2007)
cis-Hydroxylation of a synthetic steroid intermediate with iodine, silver acetate and wet acetic acid.
Woodward RB and Brutcher Jr FV.
Journal of the American Chemical Society, 80(1), 209-211 (1958)
Silver acetate-assisted formation of amides from acyl chlorides.
Leggio A, et al.
Tetrahedron Letters, 56(1), 199-202 (2015)
A Pupka et al.
European journal of vascular and endovascular surgery : the official journal of the European Society for Vascular Surgery, 41(1), 61-67 (2010-11-26)
The aim of our study was to evaluate the effectiveness of in situ revascularisation with the use of arterial homografts and silver-coated prostheses in the treatment of aortic graft infection. A total of 77 consecutive patients (74 males, three females
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