A7149
硫氰酸铵
crystals
别名:
硫氰化铵
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关于此项目
线性分子式:
NH4SCN
化学文摘社编号:
分子量:
76.12
NACRES:
NA.55
PubChem Substance ID:
eCl@ss:
38060604
UNSPSC Code:
12352300
EC Number:
217-175-6
MDL number:
Beilstein/REAXYS Number:
3595135
Assay:
≥98% NaOH basis (titration)
Form:
crystals
Solubility:
water: soluble 76.1 g/L at 20 °C
InChI key
SOIFLUNRINLCBN-UHFFFAOYSA-N
InChI
1S/CHNS.H3N/c2-1-3;/h3H;1H3
SMILES string
N.SC#N
vapor pressure
0.000114 hPa ( 20 °C)
assay
≥98% NaOH basis (titration)
color
white
pH
4.8 (20.1 °C, 1070 g/L)
mp
152-154 °C (lit.)
solubility
water: soluble 76.1 g/L at 20 °C
Quality Level
form
crystals
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General description
硫氰酸铵是通常用于有机化合物硫氰化反应的铵盐。
Application
硫氰酸铵（ATC）已用于制备与K14E7小鼠皮肤分离的表皮片，以进行免疫荧光染色。
它可用于合成以下物质：
硫氰酸铵（ATC）可用于以下合成过程：
它可用于合成以下物质：
硫氰酸铵（ATC）可用于以下合成过程：
- 石墨碳氮化物。
- 三维氮和硫共掺杂石墨烯框架 (N/S-GFs)。
- 在N-甲基咪唑存在下，通过与α-卤代酮羰基反应取代2-氨基噻唑衍生物。
- 在LiBF4存在下，由相应的环氧乙烷生成噻吩。
- 在不存在溶剂的情况下，通过与苯并酰肼酸和酰氯的多组分反应生成1,2,4-三唑-3-硫酮。
signalword
Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1
supp_hazards
存储类别
13 - Non Combustible Solids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
Nor Malia Abd Warif et al.
PloS one, 10(5), e0127155-e0127155 (2015-05-21)
It has previously been shown that expression of human papillomavirus type 16 (HPV) E7 in epidermis causes hyperplasia and chronic inflammation, characteristics of pre-malignant lesions. Importantly, E7-expressing epidermis is strongly immune suppressed and is not rejected when transplanted onto immune
Thiocyanation of aromatic and heteroaromatic compounds using ammonium thiocyanate and I2O5.
Wu J, et al.
Synthetic Communications, 38(14), 2367-2373 (2008)
Regioselective thiocyanation of aromatic and heteroaromatic compounds using ammonium thiocyanate and oxone.
Wu G, et al.
Tetrahedron Letters, 46(35), 5831-5834 (2005)
NBS or DEAD as effective reagents in α-thiocyanation of enolizable ketones with ammonium thiocyanate.
Reddy BVS, et al.
Tetrahedron Letters, 52(13), 1432-1435 (2011)
Convenient and simple synthesis of 2-aminothiazoles by the reaction of α-halo ketone carbonyls with ammonium thiocyanate in the presence of N-methylimidazole.
Meshram HM, et al.
Tetrahedron Letters, 53(39), 5265-5269 (2012)
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