M46837
甲酸甲酯
reagent grade, 97%
别名:
蚁酸甲酯
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关于此项目
线性分子式:
HCO2CH3
化学文摘社编号:
分子量:
60.05
UNSPSC Code:
12352108
NACRES:
NA.21
PubChem Substance ID:
EC Number:
203-481-7
Beilstein/REAXYS Number:
1734623
MDL number:
Grade:
reagent grade
Assay:
97%
Bp:
32-34 °C (lit.)
Vapor pressure:
32.81 psi ( 55 °C)
9.21 psi ( 20 °C)
9.21 psi ( 20 °C)
产品名称
甲酸甲酯, reagent grade, 97%
InChI key
TZIHFWKZFHZASV-UHFFFAOYSA-N
InChI
1S/C2H4O2/c1-4-2-3/h2H,1H3
SMILES string
[H]C(=O)OC
grade
reagent grade
vapor density
2.1 (vs air)
vapor pressure
32.81 psi ( 55 °C)
9.21 psi ( 20 °C)
assay
97%
form
liquid
autoignition temp.
842 °F
expl. lim.
23 %
dilution
(for analytical testing)
impurities
≤3% methyl alcohol
refractive index
n20/D 1.343 (lit.)
pH
4.0-5.0 (20 °C, 200 g/L)
bp
32-34 °C (lit.)
mp
−100 °C (lit.)
density
0.974 g/mL at 20 °C (lit.)
Quality Level
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Application
Methyl formate may be used to prepare formamides via amine formaylation.
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 1 - STOT SE 1 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
-2.2 °F - closed cup
flash_point_c
-19 °C - closed cup
法规信息
危险化学品
此项目有
Catalytic reaction of methyl formate with amines to formamides.
Deutsch J, et al.
Tetrahedron, 65(50), 10365-10369 (2009)
Rotational isomerism in methyl formate and methyl acetate; a low-temperature matrix infrared study using thermal molecular beams.
Blom CE and Gunthard HH.
Chemical Physics Letters, 84(2), 267-271 (1981)
Methyl formate as a new building block in C1 chemistry.
Lee JS, et al.
Applied Catalysis, 57(1), 1-30 (1990)
Jean-François Bilodeau et al.
Prostaglandins, leukotrienes, and essential fatty acids, 164, 102215-102215 (2020-12-05)
Cancer has been associated with increased oxidative stress and deregulation of bioactive oxylipins derived from long-chain polyunsaturated fatty acids (LC-PUFA) like arachidonic acid (AA). There is a debate whether ω-3 LC-PUFA could promote or prevent prostate tumor growth through immune
Marine S Da Silva et al.
Prostaglandins, leukotrienes, and essential fatty acids, 126, 64-71 (2017-10-17)
This study aimed to determine whether dairy macronutrients alter markers of inflammation and oxidative stress in endothelial cells. Human endothelial cells (HUVEC) were treated with ruminant trans fatty acids (rTFA), either trans-vaccenic acid (tVA) or trans-palmitoleic acid (tPA), whey protein
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