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Merck
CN

M46837

Sigma-Aldrich

甲酸甲酯

reagent grade, 97%

别名:

蚁酸甲酯

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关于此项目

线性分子式:
HCO2CH3
化学文摘社编号:
分子量:
60.05
Beilstein:
1734623
EC 号:
MDL编号:
UNSPSC代码:
12352108
PubChem化学物质编号:
NACRES:
NA.21
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等级

reagent grade

质量水平

蒸汽密度

2.1 (vs air)

蒸汽压

32.81 psi ( 55 °C)
9.21 psi ( 20 °C)

方案

97%

表单

liquid

自燃温度

842 °F

expl. lim.

23 %

dilution

(for analytical testing)

杂质

≤3% methyl alcohol

折射率

n20/D 1.343 (lit.)

pH值(酸碱度)

4.0-5.0 (20 °C, 200 g/L)

沸点

32-34 °C (lit.)

mp

−100 °C (lit.)

密度

0.974 g/mL at 20 °C (lit.)

SMILES字符串

[H]C(=O)OC

InChI

1S/C2H4O2/c1-4-2-3/h2H,1H3

InChI key

TZIHFWKZFHZASV-UHFFFAOYSA-N

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应用

Methyl formate may be used to prepare formamides via amine formaylation.

警示用语:

Danger

危险分类

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 1 - STOT SE 1 - STOT SE 3

靶器官

Respiratory system

储存分类代码

3 - Flammable liquids

WGK

WGK 2

闪点(°F)

-2.2 °F - closed cup

闪点(°C)

-19 °C - closed cup

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Rotational isomerism in methyl formate and methyl acetate; a low-temperature matrix infrared study using thermal molecular beams.
Blom CE and Gunthard HH.
Chemical Physics Letters, 84(2), 267-271 (1981)
Marine S Da Silva et al.
Prostaglandins, leukotrienes, and essential fatty acids, 126, 64-71 (2017-10-17)
This study aimed to determine whether dairy macronutrients alter markers of inflammation and oxidative stress in endothelial cells. Human endothelial cells (HUVEC) were treated with ruminant trans fatty acids (rTFA), either trans-vaccenic acid (tVA) or trans-palmitoleic acid (tPA), whey protein
Methyl formate as a new building block in C1 chemistry.
Lee JS, et al.
Applied Catalysis, 57(1), 1-30 (1990)
Jean-François Bilodeau et al.
Prostaglandins, leukotrienes, and essential fatty acids, 164, 102215-102215 (2020-12-05)
Cancer has been associated with increased oxidative stress and deregulation of bioactive oxylipins derived from long-chain polyunsaturated fatty acids (LC-PUFA) like arachidonic acid (AA). There is a debate whether ω-3 LC-PUFA could promote or prevent prostate tumor growth through immune
Catalytic reaction of methyl formate with amines to formamides.
Deutsch J, et al.
Tetrahedron, 65(50), 10365-10369 (2009)

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