88535
硫代甲肼
purum p.a., suitable for electron microscopy, ≥99.0% (N)
别名:
硫代卡巴肼
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关于此项目
线性分子式:
(NH2NH)2CS
化学文摘社编号:
分子量:
106.15
EC Number:
218-769-8
UNSPSC Code:
12352200
PubChem Substance ID:
Beilstein/REAXYS Number:
506657
MDL number:
InChI key
LJTFFORYSFGNCT-UHFFFAOYSA-N
InChI
1S/CH6N4S/c2-4-1(6)5-3/h2-3H2,(H2,4,5,6)
SMILES string
NNC(=S)NN
grade
purum p.a.
assay
≥99.0% (N)
form
crystals
technique(s)
electron microscopy: suitable
mp
171-174 °C (dec.) (lit.)
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Application
Thiocarbohydrazide is used in silver proteinate specific and OTO-method (osmium-thiocarbohydrazide-osmium) methods for staining carbohydrates in electron microscopy. Thiocarbohydrazide may be used in the organic synthesis of metal ion coordinating compounds.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 2 Oral
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Amit Kumar Sharma et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 78(1), 337-342 (2010-11-26)
2,6-diacetyl pyridine based ligand was synthesized by the reaction of 2,6-diacetyl pyridine with thiocarbohydrazide in presence of acetic acid. The coordination compounds with Cr(III) and Ni(II) metal ions having [Cr(L)X]X2 and [Ni(L)X]X compositions (where L=ligand and X=NO3-, Cl- and CH3COO-)
D P Singh et al.
Journal of enzyme inhibition and medicinal chemistry, 22(2), 177-182 (2007-05-24)
A novel series of complexes of the type [M(TML)X2]; where TML is Tetradentate Macrocyclic Ligand; M = Co(II), Ni(II), Cu(II), Zn(II)or Cd(II); X = Cl-, CH3COO- or NO3- have been synthesized by template condensation of glyoxal and thiocarbohydrazide in the
D Levanon et al.
The Histochemical journal, 31(1), 71-73 (1999-07-16)
Samples from seven sectors of the rabbit knee articular cartilage were shaved and prepared for the scanning electron microscope using either tannic acid, thiocarbohydrazide or nothing (control). Surface morphology was found to be more typical to a given sector and
Debabrata Maity et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(40), 11152-11161 (2011-09-02)
We present novel Schiff base ligands julolidine-carbonohydrazone 1 and julolidine-thiocarbonohydrazone 2 for selective detection of Cu(2+) in aqueous medium. The planar julolidine-based ligands can sense Cu(2+) colorimetrically with characteristic absorbance in the near-infrared (NIR, 700-1000 nm) region. Employing molecular probes
E A Dunnebier et al.
Hearing research, 90(1-2), 139-148 (1995-10-01)
The stereociliar structures of the guinea-pig cochlear organ of Corti were studied at low-voltage (1-5 kV) with field-emission scanning electron microscope (SEM) using various pre- and post-fixation methods, such as OTOTO (OsO4/thiocrbohydrazide/OsO4/thiocarbohydrazide/OsO4) and TAO (tannic acid/arginine/OsO4), and different dissection procedures
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