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Merck
CN

88535

硫代甲肼

purum p.a., suitable for electron microscopy, ≥99.0% (N)

别名:

硫代卡巴肼

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关于此项目

线性分子式:
(NH2NH)2CS
化学文摘社编号:
分子量:
106.15
EC Number:
218-769-8
UNSPSC Code:
12352200
PubChem Substance ID:
Beilstein/REAXYS Number:
506657
MDL number:
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InChI key

LJTFFORYSFGNCT-UHFFFAOYSA-N

InChI

1S/CH6N4S/c2-4-1(6)5-3/h2-3H2,(H2,4,5,6)

SMILES string

NNC(=S)NN

grade

purum p.a.

assay

≥99.0% (N)

form

crystals

technique(s)

electron microscopy: suitable

mp

171-174 °C (dec.) (lit.)

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Application

Thiocarbohydrazide is used in silver proteinate specific and OTO-method (osmium-thiocarbohydrazide-osmium) methods for staining carbohydrates in electron microscopy. Thiocarbohydrazide may be used in the organic synthesis of metal ion coordinating compounds.

pictograms

Skull and crossbones

signalword

Danger

Hazard Classifications

Acute Tox. 2 Oral

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Amit Kumar Sharma et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 78(1), 337-342 (2010-11-26)
2,6-diacetyl pyridine based ligand was synthesized by the reaction of 2,6-diacetyl pyridine with thiocarbohydrazide in presence of acetic acid. The coordination compounds with Cr(III) and Ni(II) metal ions having [Cr(L)X]X2 and [Ni(L)X]X compositions (where L=ligand and X=NO3-, Cl- and CH3COO-)
F Murata et al.
Journal of electron microscopy, 41(1), 14-20 (1992-02-01)
Sulfated glycoconjugates in epithelial cells and mesenchymal cells were investigated after staining with high iron diamine-thiocarbohydrazide-silver proteinate. One purpose of the experiment was to apply a new physical developed to the staining. Instead of silver nitrate, silver lactate or silver
O Fujimori et al.
The Histochemical journal, 23(2), 91-99 (1991-02-01)
A method has been developed for the histochemical demonstration of unsaturated lipids in light microscopy. It is a peracetic acid-thiocarbohydrazide-silver protein sequence followed by a physical development procedure. In the present study on paraffin and cryostat sections of liver, brain
D H Yang et al.
The Histochemical journal, 28(1), 33-43 (1996-01-01)
The ontogeny of sulphated glycoconjugate-producing cells in the rat fundic gland has been studied using high iron diamine (HID), Alcian Blue (AB) at pH 1.0, high iron diamine in combination with Alcian Blue at pH 2.5 (HID-AB), cationic colloidal gold
K S Siddiqi et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 67(3-4), 995-1002 (2006-11-07)
Sn(tch)2{MCl2}2 was prepared from the precursor Sn(tch)2 and MCl2. It was subsequently allowed to react with diethyldithiocarbamate which yielded the trinuclear complexes of the type Sn(tch)2{M2(dtc)4}, where tch=thiocarbohydrazide, M=Mn(II), Fe(II), Co(II), Ni(II), Cu(II) and dtc=diethyldithiocarbamate. They were characterized on the

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