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96631

Sigma-Aldrich

双（2,2′-联吡啶）-4′-甲基-4-羧基吡啶-钌-N-琥珀酰亚胺酯-双（六氟磷酸盐）

BioReagent, suitable for fluorescence

别名:

Ru(bpy)2(mcbpy-O-Su-ester)(PF6)2

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About This Item

经验公式（希尔记法）:
C36H29F12N7O4P2Ru
CAS号:
136724-73-7
分子量:
1014.66
MDL编号:
MFCD02683415
UNSPSC代码:
12352108
PubChem化学物质编号:
57653770
NACRES:
NA.32

产品线

BioReagent

质量水平

100

表单

powder

荧光

λex 458 nm; λem 628 nm in 0.1 M phosphate pH 7.0

适用性

suitable for fluorescence

运输

dry ice

储存温度

−20°C

SMILES字符串

[Ru++].F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.c1ccc(nc1)-c2ccccn2.c3ccc(nc3)-c4ccccn4.Cc5ccnc(c5)-c6cc(ccn6)C(=O)ON7C(=O)CCC7=O

InChI

1S/C16H13N3O4.2C10H8N2.2F6P.Ru/c1-10-4-6-17-12(8-10)13-9-11(5-7-18-13)16(22)23-19-14(20)2-3-15(19)21;2*1-3-7-11-9(5-1)10-6-2-4-8-12-10;2*1-7(2,3,4,5)6;/h4-9H,2-3H2,1H3;2*1-8H;;;/q;;;2*-1;+2

InChI key

UQJZJWDQEYXDCR-UHFFFAOYSA-N

相关类别

应用

双(2,2′-联吡啶)-4′-甲基-4-羧基联吡啶钌N-双六氟磷酸盐用于：
  • 用作制备钌标记剂溶液（RuC）的组分
  • 在质谱流式细胞分析时
  • 合成钌（Ru）明胶
  • 制备参与适体-磁珠电化学发光（ECL）夹心测定的链霉亲和素-Ru(bpy)32+混合物

用于氨基酸侧链胺酰化的钌络合物的活化酯。

特点和优势

该染料具有长荧光寿命（接近500纳秒），具有高光稳定性和良好的水溶性，且不会产生染料-染料相互作用和大的斯托克斯位移。

包装

无底玻璃瓶。内含物装在插入的融合锥内。

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCL3893
BCCL9012
BCCL7743
BCCK5597
BCCJ5581

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Bruno J, et al.
Microchemical Journal, Devoted to the Application of Microtechniques in All Branches of Science, 115, 32-38 (2014)
Zhejian Li et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 35(2), 195-199 (2018-10-10)
A novel gold nanoprobe for a sensitive and simple determination of a prostate-specific antigen (PSA) was designed on the basis of homogeneous detection and a peptide cleavage reaction. The gold nanoprobe (AuNPs-peptide-Ru1) consisted of a specific peptide tagged with a
B M Peek et al.
International journal of peptide and protein research, 38(2), 114-123 (1991-08-01)
Boc-L-Lysine derivatives and lysine-containing peptides bearing the electron donor 10H-phenothiazine (PTZ) or the redox chromophore tris(2,2'-bipyridine)ruthenium(II) dication ([Rub3]2+, where b is 2,2'-bipyridine) have been synthesized and characterized. SeO2 oxidation (53% yield) of 4,4'-dimethyl-2,2'-bipyridine, Ag2O oxidation (85% yield) of the monoaldehyde
Bernd Geisser et al.
Inorganic chemistry, 38(9), 2030-2037 (2001-10-24)
The pH-dependent photophysical properties of a series of polypyridyl ruthenium-substituted amino acids were investigated by steady-state and time-resolved luminescence spectroscopy. [H(3)N-DAPA(Rub(2)m)-OH](PF(6))(3) (1), [H(3)N-DABA(Rub(2)m)-OH](PF(6))(3) (2), [H(3)N-Orn(Rub(2)m)-OH](PF(6))(3) (3), and [H(3)N-Lys(Rub(2)m)-OH](PF(6))(3) (4) were obtained by formation of an amide link between the omega-NH(2)
Fluorometric enzymatic autoindicating biosensor for H2O2 determination based on modified catalase
Ortega E, et al.
Biosensors And Bioelectronics, 41, 150-156 (2013)
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