InChI
1S/C3H2N2/c4-2-1-3-5/h1H2
InChI key
CUONGYYJJVDODC-UHFFFAOYSA-N
SMILES string
N#CCC#N
assay
~98%
form
crystalline
color
off-white to brown
bp
220 °C (lit.)
mp
30-32 °C (lit.)
density
1.049 g/mL at 25 °C (lit.)
storage temp.
2-8°C
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signalword
Danger
Hazard Classifications
Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Sens. 1
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
186.8 °F - closed cup
flash_point_c
86 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
法规信息
新产品
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Xin Feng et al.
Journal of the American Chemical Society, 134(48), 19942-19947 (2012-11-16)
Switchable reaction patterns of β-substituted cyclic enones via amine-based dienamine activation are reported. While γ-regioselective vinylogous Michael addition was observed with alkylidenemalononitriles, a completely different [4 + 2] cycloaddition was obtained with allylidene- or alkynylidenemalononitrile substrates, affording densely substituted bicyclo[2.2.2]octanes
Xianxing Jiang et al.
Chemical communications (Cambridge, England), 47(29), 8289-8291 (2011-06-23)
We present here the synthesis of dicyano-2-methylenebut-3-enoates as novel Diels-Alder dienes through an efficient PPh(3)-catalyzed strategy, and an unprecedented PPh(3)-catalyzed addition/all-carbon-based asymmetric inverse-electron-demand Diels-Alder sequence reaction is disclosed for the first time.
Dayong Tian et al.
Chemosphere, 88(8), 994-1000 (2012-04-17)
Organic chemicals usually coexist as a mixture in the environment, and the mixture toxicity of organic chemicals has received increased attention. However, research regarding the joint effects of reactive chemicals is lacking. In this study, we examined two kinds of
Xiao-Gang Yin et al.
Organic & biomolecular chemistry, 10(8), 1506-1509 (2012-01-11)
A cascade Michael/Michael/oxa-Michael reaction between curcumins and isatylidene malononitriles has been developed. Multicyclic spirooxindoles were prepared in excellent yields and diastereoselectivities. DMAP was found to catalyze this transformation efficiently under mild reaction conditions.
Jonghan Shin et al.
Journal of Alzheimer's disease : JAD, 26 Suppl 3, 135-145 (2011-10-06)
2-(1-{6-[(2-[fluorine-18]fluoroethyl)(methyl)amino]-2-naphthyl}-ethylidene)malononitrile (FDDNP) is the first positron emission tomography (PET) molecular imaging probe to visualize Alzheimer's disease (AD) pathology in living humans. The most unique features of FDDNP are that (1) it is the only currently available radiotracer to image neurofibrillary
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