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Merck
CN

P2171

3-Pyridinealdehyde adenine dinucleotide

别名:

3-Pyridinealdehyde-DPN

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关于此项目

经验公式(希尔记法):
C21H26N6O14P2
化学文摘社编号:
分子量:
648.41
UNSPSC Code:
41106305
PubChem Substance ID:
MDL number:
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assay

≥90%

storage temp.

−20°C

SMILES string

Nc1ncnc2n(cnc12)C3OC(COP(O)(=O)OP(O)(=O)OCC4OC(C(O)C4O)[N]5=CC(C=O)=CC=C5)C(O)C3O

Application

3-Pyridinealdehyde adenine dinucleotide is an analogue of NAD that may be used to study the structure and function of NAD binding enzymes such as glyceraldehyde 3-phosphate dehydrogenase, NAD malic enzymes, lactate dehydrogenase and saccharopine dehydrogenase from S. cerevisiae.

Other Notes

Analog of NAD


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R D LaReau et al.
Biochemistry, 31(17), 4174-4180 (1992-05-05)
Lactate dehydrogenase catalyzes the stereospecific hydride transfer to and from the re face of the nicotinamide coenzyme. The demonstrated probability of transfer to the si face of less than 2 x 10(-8) indicates that the free energy of any diastereotopic
E J Hill et al.
The Journal of biological chemistry, 250(5), 1734-1740 (1975-03-10)
Glyceraldehyde 3-phosphate dehydrogenase (D-glyceraldehyde-3-phoshate:nicotinamide adenine dinucleotide oxidoreductase (phosphorylating), EC 1.2.1.12) forms a complex with 3-pyridinealdehyde-NAD which survives precipitation with 7% perchloric acid. The molar ratio bound 3-pyridinealdehyde-NAD to the enzyme is 2.5 to 2.9. Lactate, malate, and alcohol dehydrogenases do
Hengyu Xu et al.
Biochemistry, 46(25), 7625-7636 (2007-06-05)
A survey of NADH, alpha-Kg, and lysine analogues has been undertaken in an attempt to define the substrate specificity of saccharopine dehydrogenase and to identify functional groups on all substrates and dinucleotides important for substrate binding. A number of NAD