R0878
D-核糖1,5-双磷酸酯 钠盐 水合物
≥90% (TLC)
别名:
D-赤型-2-戊糖，1,5-双（磷酸二氢）, D-核糖1,5-二磷酸酯, RuDP
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关于此项目
经验公式（希尔记法）:
C5H12O11P2 · xNa+ · yH2O
化学文摘社编号:
分子量:
310.09 (anhydrous free acid basis)
UNSPSC代码:
12352201
NACRES:
NA.28
生物来源
synthetic (inorganic)
方案
≥90% (TLC)
表单
powder
杂质
≤16% water (Karl Fischer)
颜色
white
溶解性
water: ~50 g/L
痕量阳离子
Na: 17.1-24.6% (dry basis)
储存温度
−20°C
SMILES字符串
[P](=O)(OC[C@@H](O)[C@@H](O)C(=O)CO[P](=O)(O)O)(O)O
InChI
1S/C5H12O11P2/c6-3(1-15-17(9,10)11)5(8)4(7)2-16-18(12,13)14/h3,5-6,8H,1-2H2,(H2,9,10,11)(H2,12,13,14)/t3-,5-/m1/s1
InChI key
YAHZABJORDUQGO-NQXXGFSBSA-N
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应用
- Bio-Inspired Microreactors Continuously Synthesize Glucose Precursor from CO(2) with an Energy Conversion Efficiency 3.3 Times of Rice.：该研究用D-核酮糖-1,5-二磷酸钠盐水合物与CO₂通过生物启发式微反应器合成葡萄糖前体。这种方法的能量转换效率远高于大米，具有高效固碳和生物工程应用潜力(Zhu et al., 2024)。
- Designing Stacked Assembly of Type III Rubisco for CO₂ Fixation with Higher Efficiency.：该研究通过堆积装配III型Rubisco（核酮糖二磷酸羧化酶）提高CO₂固定效率，其中用到D-核酮糖-1,5-二磷酸钠盐水合物。这种创新方法改进了碳捕获和利用方面的代谢工程(Zeng et al., 2022)。
- Continuous artificial synthesis of glucose precursor using enzyme-immobilized microfluidic reactors.：该研究用微流控反应器固定酶连续合成葡萄糖前体，反应用到D-核酮糖-1,5-二磷酸钠盐水合物。说明本品在可放大生物生产过程中的应用前景(Zhu et al., 2019)。
生化/生理作用
1,5-双磷酸核糖（RuBP）是加尔文循环的一个组成部分，被核糖双磷酸羧化酶/加氧酶（RuBisCO）代谢为 3-磷酸甘油酯（G3P）。RuBP 用于鉴定、鉴别和表征核糖双磷酸羧化酶/加氧酶（RuBisCO）。
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
法规信息
涉药品监管产品
此项目有
Robert E Sharwood et al.
Journal of experimental botany, 67(10), 3137-3148 (2016-04-29)
Plants operating C3 and C4 photosynthetic pathways exhibit differences in leaf anatomy and photosynthetic carbon fixation biochemistry. Fully understanding this underpinning biochemical variation is requisite to identifying solutions for improving photosynthetic efficiency and growth. Here we refine assay methods for
S K Guha et al.
Archives of biochemistry and biophysics, 250(2), 513-518 (1986-11-01)
Ribose-1,5-bisphosphate is synthesized in a reaction that uses ribose-1(or 5)-P as the phosphoryl acceptor and the acyl-P of 3-phosphoglyceryl phosphate as the donor. Glucose-1,6-bisphosphate is synthesized in a similar reaction. The relative activity with the two substrates remains unchanged over
Maria L B Magalhães et al.
Biochemistry, 47(24), 6499-6507 (2008-05-27)
Riboflavin is biosynthesized by most microorganisms and plants, while mammals depend entirely on the absorption of this vitamin from the diet to meet their metabolic needs. Therefore, riboflavin biosynthesis appears to be an attractive target for drug design, since appropriate
Hairong Huang et al.
Microbiology (Reading, England), 154(Pt 3), 736-743 (2008-03-04)
Decaprenylphosphoryl-d-arabinose (DPA) has been shown to be the donor of the essential d-arabinofuranosyl residues found in the cell wall of Mycobacterium tuberculosis. DPA is formed from phosphoribose diphosphate in a four-step process. The first step is the nucleophilic replacement of
E Ishikawa et al.
The Journal of biological chemistry, 265(31), 18875-18878 (1990-11-05)
Ribose 1,5-bisphosphate (Rib-1,5-P2), a newly discovered activator of rat brain phosphofructokinase, forms rapidly during the initiation of glycolytic flux and disappears within 20 s (Ogushi, S., Lawson, J.W. R., Dobson, G.P., Veech, R.L., and Uyeda, K. (1990) J. Biol. Chem.
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