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Merck
CN

18514

硅藻土

greener alternative

calcined, purified

别名:

纤毛虫土

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化学文摘社编号:
UNSPSC Code:
12352200
PubChem Substance ID:
MDL number:
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InChI

1S/O2Si/c1-3-2

InChI key

VYPSYNLAJGMNEJ-UHFFFAOYSA-N

form

powder

quality

calcined, purified

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

impurities

≤1% HCl solubles

loss

≤1% loss on ignition

anion traces

chloride (Cl-): ≤200 mg/kg, sulfate (SO42-): ≤500 mg/kg

cation traces

Fe: ≤500 mg/kg

greener alternative category

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General description

Kieselguhr (diatomite, infusorial earth) is the fossilized skeletons of diatom algae. It is mainly made up of silica with many unique features like high porosity, small particle size, low density and thermal conductivity. It is primarily utilized as a source to manufacture filter aids, fire-bricks and adsorbents. Kieselguhr is the main component of the Berkefeld filter used for purifying water. It is also utilized in the filtration process of beer brewing.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalysis. Find details here.

Application

Kieselguhr (infusorial earth) may be used in the following processes:
  • Estimation of total fats.
  • As a catalyst in the synthesis of ketones and aldehydes via oxidation of corresponding oximes with manganese dioxide.
  • Green synthesis of β-nitroalkenes via Michael addition of 1,3-dicarbonyl compounds, by a grinding method in the absence of solvent and catalyst.
  • Preparation of KMnO4-kieselguhr reagent for use in the oxidation of primary alcohols to aldehydes with shorter reaction time.
Used for greener amide bond formation from amines and carboxylic acids after thermal activation at high temperature.

Clean, reusable and low cost heterogeneous catalyst for amide synthesis

pictograms

Health hazard

signalword

Danger

hcodes

Hazard Classifications

STOT RE 1 Inhalation

target_organs

Lungs

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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分析证书(COA)

Lot/Batch Number

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Catalyst-free and solvent-free Michael addition of 1,3-dicarbonyl compounds to nitroalkenes by a grinding method.
Xie ZB, et al.
Beilstein Journal of Organic Chemistry, 8(1), 534-538 (2012)
Removal of uranium from aqueous solutions by diatomite (Kieselguhr).
Olmez AS, et al.
J. Radioanal. Nucl. Chem., 240(3), 973-976 (1999)
Manufacture of ceramic bricks using recycled brewing spent Kieselguhr.
Ferraz E, et al.
Materials and Manufacturing Processes, 26(10), 1319-1329 (2011)
Oxidation of alcohols to carbonyl compounds with a new potassium permanganate adsorbed on kieselguhr reagent.
Lou J-D and Lou WX.
Synthetic Communications, 27(21), 3697-3699 (1997)
Household Water Treatment following Emergencies and Disasters- A Review
Gambhir RS, et al.
Indian Journal of Public Health Research & Development, 4(3), 249-252 (2013)

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