Merck
CN

CRM01342

Supelco

土菌灵

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

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别名:
5-乙氧基-3-三氯甲基-1,2,4-噻二唑, 氯唑灵
Empirical Formula (Hill Notation):
C5H5Cl3N2OS
CAS号:
分子量:
247.53
MDL编号:

等级

certified reference material
TraceCERT®

质量水平

产品线

TraceCERT®

保质期

limited shelf life, expiry date on the label

manufacturer/tradename

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

储存温度

2-8°C

SMILES string

CCOc1nc(ns1)C(Cl)(Cl)Cl

InChI

1S/C5H5Cl3N2OS/c1-2-11-4-9-3(10-12-4)5(6,7)8/h2H2,1H3

InChI key

KQTVWCSONPJJPE-UHFFFAOYSA-N

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一般描述

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ. Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate. Download your certificate at: http://www.sigma-aldrich.com

Etridiazole is a fungicide primarily effective against oomycetes and widely used in controlling Pythium and Phytophthora species on agricultural and horticultural crops. Etridiazole causes the hydrolysis of cell membrane phospholipids into free fatty acids and lysophosphatides, leading to the lysis of membranes in fungi.


The drinking water standards have regulated a maximum contaminant level (MCL) for Etridiazole in treated waters. Australian drinking water guidelines set an MCL at 0.1 mg L-1. The European Union (EU) drinking water standards regulate a level for any pesticide at 0.0001 mg L-1 and the sum of all pesticides at 0.0005 mg L-1.

Etridiazole was included in Annex I to Directive 91/414/EEC on 1 June 2014 by Commission Directive 2011/29/EU and has been deemed to be approved under Regulation (EC) No 1107/2009, as per Commission Implementing Regulation (EU) No 540/2011, as amended by Commission Implementing Regulation (EU) No 541/2011. The inclusion in Annex I of Directive 91/414/EEC was restricted to uses of Etridiazole as a fungicide in non-soil bound systems in greenhouse. Maximum residue levels (MRLs) have been set according to Reg (EU) 2017/1777 for Etridiazole for various products of plant and animal origin from 0.05 to 0.4 mg/kg.

应用

The certified reference material can be used for the following:
  • To evaluate the teratogenic and developmental toxic effects of etridiazole on zebrafish embryos
  • Screening potential endophytic biofertilizers with fungicides tolerance and plant growth-promoting characteristics
  • To investigate the photodegradation of etridiazole by UV radiation at 254 nm during drinking water treatment
  • To determine the adsorption and desorption behavior of etridiazole and oxamyl on polyethylene sheets and polyvinyl chloride tubing used in horticulture
  • To develop a selective and sensitive analytical method for the determination of a carboxylic and a mercapturic acid metabolite of etridiazole in urine

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Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

法律信息

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

警示用语:

Warning

危险分类

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Skin Sens. 1

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

310.1 °F - open cup

闪点(°C)

154.5 °C - open cup

法规信息

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Adsorption experiments of etridiazole and oxamyl on polyethylene sheets and poly (vinyl chloride) tubing used in horticulture
Vuik J, et al.
Journal of Agricultural and Food Chemistry, 328-330 null
Teratogenic and developmental toxic effects of etridiazole on zebrafish (Danio rerio) embryos
Vasamsetti BMK
Applied Biological Chemistry, 1-10 null
Alba Brancato et al.
EFSA journal. European Food Safety Authority, 15(3), e04736-e04736 (2017-03-09)
In accordance with Article 6 of Regulation (EC) No 396/2005, the evaluating Member State (EMS), the Netherlands, received an application from Arysta LifeScience Great Britain Limited to modify the existing maximum residue levels (MRLs) for the active substance etridiazole in various
Influence of pH and Etridiazole on Pythium Species
Krasnow CS and Hau MK
HortTechnology, 367-374 null
R T van Welie et al.
Archives of toxicology, 65(8), 625-632 (1991-01-01)
Etridiazole, 5-ethoxy-3-trichloromethyl-1,2,4-thiadiazole, was orally administered to rats and human volunteers. Two metabolites of etridiazole were synthesized: 5-ethoxy-1,2,4-thiadiazole-3-carboxylic acid (ET-CA) and N-acetyl-S-(5-ethoxy-1,2,4-thiadiazol-3-yl-methyl)-L-cysteine (ET-MA). Selective and sensitive analytical procedures to determine etridiazole, the carboxylic acid ET-CA and the mercapturic acid ET-MA in

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