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经验公式(希尔记法):
C17H26ClNO3S
化学文摘社编号:
分子量:
359.91
UNSPSC Code:
41116107
PubChem Substance ID:
MDL number:
InChI
1S/C17H26ClNO3S/c1-4-14(19-22-8-6-7-18)17-15(20)10-13(11-16(17)21)9-12(3)23-5-2/h6-7,12-13,20H,4-5,8-11H2,1-3H3/b7-6+,19-14+
SMILES string
CCSC(C)CC1CC(O)=C(C(=O)C1)\C(CC)=N\OC\C=C\Cl
InChI key
SILSDTWXNBZOGF-KUZBFYBWSA-N
grade
analytical standard
packaging
ampule of 100 mg
manufacturer/tradename
Chem Service, Inc. PS-2045
technique(s)
HPLC: suitable, gas chromatography (GC): suitable
application(s)
agriculture
environmental
format
neat
storage temp.
2-8°C
Gene Information
rat ... Acaca(60581)
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General description
Clethodim is a cyclohexanedione oxime herbicide primarily used against a wide variety of broadleaf crops. Its mode of action involves the inhibition of acetyl-coenzyme A carboxylase.
Application
Clethodim may be used as a reference standard for the determination of clethodim in crops by liquid chromatography (LC) followed by liquid chromatography/mass spectrometry (LC/MS) with electrospray ionization (ESI).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3 - Skin Sens. 1
supp_hazards
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves
法规信息
新产品
此项目有
Physiological basis for antagonism of clethodim by imazapic on goosegrass (Eleusine indica (L.) Gaertn.).
Burke LC and Wilcut JW
Pesticide Biochemistry and Physiology, 76(2), 37-45 (2003)
S Ishimitsu et al.
Journal of AOAC International, 84(4), 1172-1178 (2001-08-15)
A method was developed for determination of the herbicide clethodim (C0) and its oxidation metabolites clethodim sulfoxide (C1) and clethodim sulfone (C2) in agricultural products. Upon extraction, both C0 and C1 were oxidized to C2 by m-chloroperoxybenzoic acid, and C2
Theola Louie et al.
Bioorganic & medicinal chemistry letters, 20(15), 4611-4613 (2010-06-29)
A series of dimeric 1,3-cyclohexanedione oxime ethers were synthesized and found to have significant antiplasmodial activity with IC(50)'s in the range 3-12 microM. The most active dimer was tested in the Plasmodium berghei mouse model of malaria and at a
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