V900088
1-甲基咪唑
98%, Vetec™, reagent grade
别名:
N-Methylimidazole
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关于此项目
经验公式（希尔记法）:
C4H6N2
化学文摘社编号:
分子量:
82.10
UNSPSC Code:
12352100
PubChem Substance ID:
EC Number:
210-484-7
Beilstein/REAXYS Number:
105197
MDL number:
Assay:
98%
产品名称
1-甲基咪唑, Vetec™, reagent grade, 98%
InChI key
MCTWTZJPVLRJOU-UHFFFAOYSA-N
InChI
1S/C4H6N2/c1-6-3-2-5-4-6/h2-4H,1H3
SMILES string
Cn1ccnc1
grade
reagent grade
vapor pressure
0.4 mmHg ( 20 °C)
product line
Vetec™
assay
98%
autoignition temp.
977 °F
expl. lim.
15.7 %
greener alternative product characteristics
Catalysis
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sustainability
Greener Alternative Product
bp
198 °C (lit.)
mp
−6 °C (lit.)
density
1.03 g/mL at 25 °C (lit.)
greener alternative category
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General description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of the 12 Principles of Green Chemistry. This product has been enhanced for catalysis. Find details here.
Legal Information
Vetec is a trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Repr. 2 - Skin Corr. 1B
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 2
flash_point_f
197.6 °F - closed cup
flash_point_c
92 °C - closed cup
Fumitoshi Shibahara et al.
The Journal of organic chemistry, 77(19), 8815-8820 (2012-09-15)
Synthetic methods for triarylated azoles containing three different aryl groups via one-pot sequential multiple C-H bond arylations are described. The one-pot sequential diarylation of C5-monoarylated azoles was achieved by the simple sequential addition of two different aryl iodides with a
Chih-Chin Tsou et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(47), 13358-13366 (2011-10-19)
S-nitrosation of the coordinated thiolate of dinitrosyl iron complexes (DNICs) to generate S-nitrosothiols (RSNOs) was demonstrated. Transformation of [{(NO)(2)Fe(μ-StBu)}(2)] (1-tBuS) into the {Fe(NO)(2)}(9) DNIC [(NO)(2)Fe(StBu)(MeIm)] (2-MeIm) occurs under addition of 20 equiv of 1-methylimidazole (MeIm) into a solution of 1-tBuS in
Wen-Xin Chen et al.
The Journal of organic chemistry, 77(20), 9236-9239 (2012-10-02)
We report herein that amides are excellent N-sources in the NHC-Pd(II)-Im complex 1 catalyzed amination of aryl chlorides. In the presence of KO(t)Bu, various aryl chlorides and amides can react smoothly to give the corresponding aminated products in moderate to
Fumitoshi Shibahara et al.
The Journal of organic chemistry, 76(8), 2680-2693 (2011-03-17)
Direct triarylation and sequential triarylation reactions of simple azoles catalyzed by [Pd(phen)(2)]PF(6) are described. Simple azoles, such as N-methylimidazole, thiazole, and oxazole, were observed to undergo triaryaltion reactions even at their C4 positions when treated with aryl iodides in the
Marc Steichen et al.
Dalton transactions (Cambridge, England : 2003), 43(32), 12329-12341 (2014-07-06)
New homoleptic and heteroleptic zinc(ii)-containing liquid metal salts with N-alkylimidazole (AlkIm) ligands and bis(trifluoromethylsulfonyl)imide (Tf2N(-)) anions are described. The general formulae of the complexes are [Zn(AlkIm)6][Tf2N]2 and [Zn(AlkIm)6-x(AlkIm')x][Tf2N]2. Single-crystal X-ray diffraction revealed that, in the solid state, the cations consist
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