蒸汽密度
1.11 (vs air)
蒸汽压
410 mmHg ( 50 °C)
97.68 mmHg ( 20 °C)
等级
p.a.
方案
99.9%
自燃温度
725 °F
expl. lim.
36 %
折射率
n20/D 1.329 (lit.)
沸点
64.7 °C (lit.)
mp
−98 °C (lit.)
密度
0.791 g/mL at 25 °C (lit.)
SMILES字符串
CO
InChI
1S/CH4O/c1-2/h2H,1H3
InChI key
OKKJLVBELUTLKV-UHFFFAOYSA-N
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一般描述
Methanol (carbinol or methyl alcohol or wood alcohol) is a primary aliphatic alcohol miscible in water. It′s a polar solvent used in many organic synthesis reactions. Recently, it has been used in direct methanol fuel cell (DMFC) technology and in the production of gasoline, olefins, and hydrocarbons.
应用
Methanol can be used:
- In combination with magnesium as a reagent for the reduction of ozonides and peroxides chemoselectively.
- In combination with NaNO2 and HCl as a reagent in the diazotization of arylamines.
- As a solvent in many organic reactions like C-C bond cleavage, reduction, cycloaddition, and amination.
警示用语：
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - STOT SE 1
靶器官
Eyes,Central nervous system
储存分类代码
3 - Flammable liquids
WGK
WGK 2
闪点(°F)
49.5 °F - closed cup
闪点(°C)
9.7 °C - closed cup
法规信息
新产品
此项目有
A new simplified protocol for copper (I) alkyne-azide cycloaddition reactions using low substoichiometric amounts of copper (II) precatalysts in methanol
Buckley B, et al.
Synlett, 27(01), 51-56 (2016)
Magnesium/methanol: An effective reducing agent for peroxides
Dai P, et al.
The Journal of Organic Chemistry, 69(8), 2851-2852 (2004)
One-pot sequential 1, 4-and 1, 2-reductions of α,β-unsaturated δ-lactones to the corresponding δ-lactols with CuCl and NaBH4 in methanol
Matsumoto Y and Yonaga M
Synlett, 25(12), 1764-1768 (2014)
A reductive amination of carbonyls with amines using decaborane in methanol
Bae J, et al.
Journal of the Chemical Society, Part 1, 27(2), 145-146 (2000)
Methanol-promoted Borylation of Arylamines: A simple and green synthetic method to Arylboronic acids and Arylboronates
Zhao C, et al.
Synlett, 25(11), 1577-1584 (2014)
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