V800040
硝酸铈(IV)铵
AR, ≥98%
别名:
硝酸铈铵
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线性分子式:
Ce(NH4)2(NO3)6
化学文摘社编号:
分子量:
548.22
UNSPSC Code:
12352302
PubChem Substance ID:
EC Number:
240-827-6
MDL number:
Assay:
≥98%
Grade:
AR
Form:
crystalline powder
InChI key
WIBGOERAEYJBOT-UHFFFAOYSA-N
InChI
1S/Ce.2HNO3.4NO3.2H3N/c;6*2-1(3)4;;/h;2*(H,2,3,4);;;;;2*1H3/q+4;;;4*-1;;
SMILES string
N.N.[Ce+4].O[N+]([O-])=O.O[N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O
grade
AR
product line
Vetec™
assay
≥98%
form
crystalline powder
anion traces
sulfate (SO42-): ≤0.05%
cation traces
Fe: ≤0.1%
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Legal Information
Vetec is a trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Ox. Sol. 2 - Skin Corr. 1B - Skin Sens. 1A
存储类别
5.1B - Oxidizing hazardous materials
wgk
WGK 3
法规信息
新产品
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Ahmad Shaabani et al.
Chemical & pharmaceutical bulletin, 56(1), 79-81 (2008-01-08)
The direct conversion of alpha-hydroxy ketones and alpha-keto oximes into quinoxaline derivatives in the presence of a catalytic amount of ceric ammonium nitrate via metal-catalyzed aerobic oxidation followed by in situ trapping with aromatic 1,2-diamines in water as a green
Alexander M Jacobine et al.
The Journal of organic chemistry, 73(18), 7409-7412 (2008-08-13)
The generation of substituted gamma-lactones can be accomplished through application of a tandem chain extension-aldol reaction, followed by CAN-mediated oxidative cleavage of the aldol product. The oxidative cleavage requires the intermediacy of a hemiketal and the presence of an alpha-heteroatom.
Aliasghar Jarrahpour et al.
Molecules (Basel, Switzerland), 12(10), 2364-2379 (2007-11-06)
It is shown that the N-(p-ethoxyphenyl) group on beta-lactams can be oxidatively removed by ceric ammonium nitrate in good yield. Fourteen new N-(p-ethoxyphenyl)-2-azetidinones 8a-n were synthesized through standard [2+2] ketene-imine cycloadditions (Staudinger reaction). Treatment of these compounds with ceric ammonium
Douglas B Grotjahn et al.
Journal of the American Chemical Society, 133(47), 19024-19027 (2011-11-09)
Organometallic iridium complexes have been reported as water oxidation catalysts (WOCs) in the presence of ceric ammonium nitrate (CAN). One challenge for all WOCs regardless of the metal used is stability. Here we provide evidence for extensive modification of many
Meng Zhou et al.
Journal of the American Chemical Society, 132(36), 12550-12551 (2010-08-25)
A series of Cp*Ir complexes can catalyze C-H oxidation, with ceric ammonium nitrate as the terminal oxidant and water as the source of oxygen. Remarkably the hydroxylation of cis-decalin and 1,4-dimethylcyclohexane proceeds with retention of stereochemistry. With H(2)O(18), cis-decalin oxidation
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