V800040
硝酸铈(IV)铵
AR, ≥98%
别名:
硝酸铈铵
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关于此项目
线性分子式:
Ce(NH4)2(NO3)6
化学文摘社编号:
分子量:
548.22
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
等级
AR
产品线
Vetec™
方案
≥98%
表单
crystalline powder
痕量阴离子
sulfate (SO42-): ≤0.05%
痕量阳离子
Fe: ≤0.1%
SMILES字符串
N.N.[Ce+4].O[N+]([O-])=O.O[N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O
InChI
1S/Ce.2HNO3.4NO3.2H3N/c;6*2-1(3)4;;/h;2*(H,2,3,4);;;;;2*1H3/q+4;;;4*-1;;
InChI key
WIBGOERAEYJBOT-UHFFFAOYSA-N
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法律信息
Vetec is a trademark of Merck KGaA, Darmstadt, Germany
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Ox. Sol. 2 - Skin Corr. 1B - Skin Sens. 1A
储存分类代码
5.1B - Oxidizing hazardous materials
WGK
WGK 3
法规信息
新产品
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Douglas B Grotjahn et al.
Journal of the American Chemical Society, 133(47), 19024-19027 (2011-11-09)
Organometallic iridium complexes have been reported as water oxidation catalysts (WOCs) in the presence of ceric ammonium nitrate (CAN). One challenge for all WOCs regardless of the metal used is stability. Here we provide evidence for extensive modification of many
Ahmad Shaabani et al.
Chemical & pharmaceutical bulletin, 56(1), 79-81 (2008-01-08)
The direct conversion of alpha-hydroxy ketones and alpha-keto oximes into quinoxaline derivatives in the presence of a catalytic amount of ceric ammonium nitrate via metal-catalyzed aerobic oxidation followed by in situ trapping with aromatic 1,2-diamines in water as a green
Alexander M Jacobine et al.
The Journal of organic chemistry, 73(18), 7409-7412 (2008-08-13)
The generation of substituted gamma-lactones can be accomplished through application of a tandem chain extension-aldol reaction, followed by CAN-mediated oxidative cleavage of the aldol product. The oxidative cleavage requires the intermediacy of a hemiketal and the presence of an alpha-heteroatom.
Meng Zhou et al.
Journal of the American Chemical Society, 132(36), 12550-12551 (2010-08-25)
A series of Cp*Ir complexes can catalyze C-H oxidation, with ceric ammonium nitrate as the terminal oxidant and water as the source of oxygen. Remarkably the hydroxylation of cis-decalin and 1,4-dimethylcyclohexane proceeds with retention of stereochemistry. With H(2)O(18), cis-decalin oxidation
Haizhou Sun et al.
Organic letters, 5(18), 3189-3192 (2003-08-29)
[reaction: see text] The removal of electroauxiliaries from peptide substrates with chemical oxidants has been examined as a method for inserting N-acyliminium ions into the peptides. To this end, it was found that both 4-methoxyphenyldimethylsilyl and 2,4-dimethoxyphenyldimethylsilyl electroauxiliaries were readily
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