V900825
四(三苯基膦)钯(0)
Vetec™, reagent grade, 98%
别名:
Pd(PPh3)4, 四(三苯基膦)钯
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关于此项目
线性分子式:
Pd[(C6H5)3P]4
化学文摘社编号:
分子量:
1155.56
EC Number:
238-086-9
UNSPSC Code:
12161600
PubChem Substance ID:
Beilstein/REAXYS Number:
6704828
MDL number:
InChI key
NFHFRUOZVGFOOS-UHFFFAOYSA-N
InChI
1S/4C18H15P.Pd/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h4*1-15H;
SMILES string
[Pd].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9.c%10ccc(cc%10)P(c%11ccccc%11)c%12ccccc%12
grade
reagent grade
product line
Vetec™
assay
98%
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
storage temp.
2-8°C
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Application
Legal Information
Vetec is a trademark of Merck KGaA, Darmstadt, Germany
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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tert-Butoxyacetylene is shown to undergo Sonogashira coupling with aryl iodides to yield aryl-substituted tert-butyl ynol ethers. These intermediates participate in a [1,5]-hydride shift, which results in the extrusion of isobutylene and the generation of aryl ketenes. The ketenes are trapped
Chanchal Chakraborty et al.
ACS applied materials & interfaces, 7(34), 19034-19042 (2015-08-19)
A platinum(II)-based, luminescent, metallo-supramolecular polymer (PolyPtL1) having an inherent dipole moment was synthesized via complexation of Pt(II) ions with an asymmetric ligand L1, containing terpyridyl and pyridyl moieties. The synthesized ligand and polymer were well characterized by various NMR techniques
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