Merck
CN
  • A simple, mild, and regioselective method for the benzylation of carbohydrate derivatives promoted by silver carbonate.

A simple, mild, and regioselective method for the benzylation of carbohydrate derivatives promoted by silver carbonate.

Carbohydrate research (2010-02-05)
Satish Malik, Vaibhav A Dixit, Prasad V Bharatam, K P Ravindranathan Kartha
摘要

A simple, mild, and regioselective method has been developed for the selective benzylation and p-methoxybenzylation of carbohydrate derivatives in high yields using Ag(2)CO(3) as the promoter. Benzylation of base-labile substrates, for which other reported methods are of little use, has been performed in high yields.

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Sigma-Aldrich
碳酸银, 99%
Sigma-Aldrich
硅藻土上的碳酸银®, extent of labeling: ~50 wt. % loading
Sigma-Aldrich
碳酸银, purum p.a., ≥99.0% (AT)