SnCl2/TiCl3-mediated deoximation of oximes in an aqueous solvent.

SnCl2/TiCl3-mediated deoximation of oximes in an aqueous solvent.

Molecules (Basel, Switzerland) (2012-03-03)

Mei-Huey Lin, Han-Jun Liu, Cheng-Yu Chang, Wei-Cheng Lin, Tsung-Hsun Chuang

摘要

A simple procedure for SnCl(2)/TiCl(3)-mediated deoximation of ketoximes in an aqueous solvent is reported. Under the conditions developed in this effort, various ketones and aldehydes are produced in good to excellent yields.

材料

产品编号

品牌

产品描述

208256

Sigma-Aldrich

氯化锡(II), reagent grade, 98%

243523

Sigma-Aldrich

氯化锡(II) 二水合物, ACS reagent, 98%

14010

Sigma-Aldrich

氯化钛(III) 溶液, 10-15% TiCl₃ basis

208035

Sigma-Aldrich

氯化锡(II) 二水合物, reagent grade, 98%

A10701

Sigma-Aldrich

苯乙酮, ReagentPlus^®, 99%

W200905

Sigma-Aldrich

苯乙酮, ≥98%, FG

31669

Sigma-Aldrich

氯化锡(II) 二水合物, puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥98%

431508

Sigma-Aldrich

氯化锡(II) 二水合物, ≥99.99% trace metals basis

474762

Sigma-Aldrich

氯化锡(II) 二水合物, ≥99.97% trace metals basis

452335

Sigma-Aldrich

氯化锡(II), anhydrous, powder, ≥99.99% trace metals basis

204722

Sigma-Aldrich

氯化锡(II), ≥99.99% trace metals basis

42163

Supelco

苯乙酮, analytical standard

00790

Sigma-Aldrich

苯乙酮, puriss. p.a., ≥99.0% (GC)

96527

Supelco

氯化锡(II) 二水合物, suitable for AAS