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Merck
CN

15329

环己烷

puriss., ≥99.5% (GC)

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关于此项目

经验公式（希尔记法）:
C6H12
化学文摘社编号:
110-82-7
分子量:
84.16
EC Number:
203-806-2
UNSPSC Code:
12191502
PubChem Substance ID:
57647362
Beilstein/REAXYS Number:
1900225
MDL number:
MFCD00003814

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vapor density

2.9 (vs air)

vapor pressure

168.8 mmHg ( 37.7 °C), 77 mmHg ( 20 °C)

grade

puriss.

assay

≥99.5% (GC)

autoignition temp.

500 °F

expl. lim.

9 %

impurities

≤0.0015% non-volatile matter, ≤0.02% water (Karl Fischer)

refractive index

n20/D 1.426 (lit.)

bp

80.7 °C (lit.)

mp

4-7 °C (lit.)

density

0.779 g/mL at 25 °C (lit.)

SMILES string

C1CCCCC1

InChI

1S/C6H12/c1-2-4-6-5-3-1/h1-6H2

InChI key

XDTMQSROBMDMFD-UHFFFAOYSA-N

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General description

Cyclohexane participates as starting reagent in the photonitrosylation process (PNC process) and affords ε-caprolactam. Its oxidation by employing various oxidants such as hydrogen peroxide, tert-butyl hydroperoxide and molecular oxygen has been reported.

Application

Cyclohexane has been used to prepare the 1.3M solution of sec-butyllithium. It may be used as starting reagent for the synthesis of adipic acid.

Other Notes

A -D suffix exists for administrative purposes only.
All -D packages are 100% the same product, same quality, same specification as the package sizes previously sold without a -D.

Pertains only in Germany: unversteuert

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Central nervous system

存储类别

3 - Flammable liquids

wgk

WGK 2

flash_point_f

-4.0 °F - closed cup

flash_point_c

-20 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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分析证书(COA)

Lot/Batch Number
1399714
SZBA0080
SZBB0270
SZBB1580
SZBB0630

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Cyclohexane oxidation continues to be a challenge.
Schuchardt ULF, et al.
Applied Catalysis A: General, 211(1), 1-17 (2001)
Eagleson M.
Concise Encyclopedia Chemistry, 168-168 (1994)
Hyperbranched nanomolecules: Regular polystyrene dendrigrafts.
Muchtar Z, et al.
Macromolecules, 34(22), 7595-7600 (2001)
Amanda L Pitts et al.
Journal of the American Chemical Society, 136(24), 8614-8625 (2014-05-16)
Carbon-hydrogen bond activation reactions of four cycloalkanes (C5H10, C6H12, C7H14, and C8H16) by the Cp'Rh(CO) fragments (Cp' = η(5)-C5H5 (Cp) or η(5)-C5Me5 (Cp*)) were modeled theoretically by combining density functional and coupled cluster theories, and their reaction rates were measured
Robert Duran et al.
Environmental science and pollution research international, 22(20), 15215-15229 (2015-02-26)
The exploration of marine Actinobacteria has as major challenge to answer basic questions of microbial ecology that, in turn, will provide useful information to exploit Actinobacteria metabolisms in biotechnological processes. The ecological functions performed by Actinobacteria in marine sediments are
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货号GTIN
536180-1G04061832565323
536180-5G04061832565330

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