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Merck
CN

339075

硼酸酐

99.98% trace metals basis

别名:

三氧化二硼

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关于此项目

经验公式(希尔记法):
B2O3
化学文摘社编号:
分子量:
69.62
PubChem Substance ID:
eCl@ss:
38120103
UNSPSC Code:
12352300
NACRES:
NA.21
EC Number:
215-125-8
MDL number:
Assay:
99.98% trace metals basis
Form:
powder
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vapor density

>1 (vs air)

Quality Level

description

for inorganic trace analysis

assay

99.98% trace metals basis

form

powder

mp

450 °C (lit.)

density

2.46 g/mL at 25 °C (lit.)

SMILES string

O=BOB=O

InChI

1S/B2O3/c3-1-5-2-4

InChI key

JKWMSGQKBLHBQQ-UHFFFAOYSA-N

Application

在使用三乙基硅烷和三氟化硼将酮选择性还原成烃的过程中,硫酸中的硼酸酐可用作洗涤剂以除去形成的副产物氟化氢气体。与羟基磷灰石结合,它可用于催化气相贝克曼重排过程,形成尼龙-6。


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pictograms

Health hazard

signalword

Danger

hcodes

Hazard Classifications

Repr. 1B

存储类别

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Vapor-phase Beckmann rearrangement of cyclohexanone oxime over boria-hydroxyapatite catalyst
Izumi Y, et al.
Chemistry Letters (Jpn), 12(10), 1649-1652 (1983)
Reduction of ketones to hydrocarbons with triethylsilane: m-nitroethylbenzene
Fry JL, et al.
Organic Syntheses, 60, 108-108 (1981)
Xiaofeng Liu et al.
Chemical communications (Cambridge, England), (27)(27), 4073-4075 (2009-07-02)
A facile strategy based on the reaction of urea and boric acid is developed for the synthesis of toxicity-free BCNO nanocrystals containing carbon impurities and which exhibit efficient multi-color fluorescence under both single-photon and two-photon excitation.



全球贸易项目编号

货号GTIN
339075-500G04061826745830
339075-100G04061826745793