产品名称
四氟对苯醌, 97%
InChI key
JKLYZOGJWVAIQS-UHFFFAOYSA-N
InChI
1S/C6F4O2/c7-1-2(8)6(12)4(10)3(9)5(1)11
SMILES string
FC1=C(F)C(=O)C(F)=C(F)C1=O
assay
97%
form
solid
mp
183-186 °C (subl.) (lit.)
functional group
fluoro
ketone
Quality Level
Application
四氟-1,4-苯醌(四氟苯喹啉)可用于制备:
- 通过氧化还原缩合反应将两个醇偶联,产生对称或不对称醚。
- Azocino[4,3-b]吲哚支架,用作制备(±)-dasycarpidone的中间体。
- 联萘酚的手性和外消旋电荷转移(CT)配合物。
General description
四氟-1,4-苯醌是一种含氟合成砌块,通常被用作氟衍生物的前体。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
ppe
dust mask type N95 (US), Eyeshields, Gloves
Complexation Behavior of Binaphthol/Tetrafluoro-1, 4-benzoquinone Charge-Transfer Complex.
Imai Y, et al.
Crystal Growth & Design, 9(5), 2393-2397 (2009)
Tetrafluoro-p-benzoquinone
Essers M and Haufe G
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
Generation and spectroscopic characterization of the 2, 3, 5, 6-tetramethoxy-1, 4-benzosemiquinone reactive intermediate.
Mattar SM, et al.
Chemical Physics Letters, 352(1), 39-47 (2002)
Ken Okamoto et al.
Journal of the American Chemical Society, 125(41), 12416-12417 (2003-10-09)
Self-promoted electron transfer from a cobalt(II) porphyrin [Co(II)OEP] to p-fluoranil (F4Q) occurs, exhibiting a second-order dependence of the electron-transfer rate with respect to the F4Q concentration due to the formation of a strong complex between the dimer radical anion [(F4Q)2*-]
A convenient method for the preparation of symmetrical or unsymmetrical ethers by the coupling of two alcohols via a new type of oxidation-reduction condensation using tetrafluoro-1, 4-benzoquinone.
Shintou T and Mukaiyama T.
Chemistry Letters (Jpn), 11, 984-985 (2003)
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