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质量水平
检测方案
97%
形式
solid
mp
183-186 °C (subl.) (lit.)
官能团
fluoro
ketone
SMILES字符串
FC1=C(F)C(=O)C(F)=C(F)C1=O
InChI
1S/C6F4O2/c7-1-2(8)6(12)4(10)3(9)5(1)11
InChI key
JKLYZOGJWVAIQS-UHFFFAOYSA-N
一般描述
四氟-1,4-苯醌是一种含氟合成砌块，通常被用作氟衍生物的前体。
应用
四氟-1,4-苯醌（四氟苯喹啉）可用于制备：
- 通过氧化还原缩合反应将两个醇偶联，产生对称或不对称醚。
- Azocino[4,3-b]吲哚支架，用作制备(±)-dasycarpidone的中间体。
- 联萘酚的手性和外消旋电荷转移(CT)配合物。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Ken Okamoto et al.
Journal of the American Chemical Society, 125(41), 12416-12417 (2003-10-09)
Self-promoted electron transfer from a cobalt(II) porphyrin [Co(II)OEP] to p-fluoranil (F4Q) occurs, exhibiting a second-order dependence of the electron-transfer rate with respect to the F4Q concentration due to the formation of a strong complex between the dimer radical anion [(F4Q)2*-]
Ben-Zhan Zhu et al.
Proceedings of the National Academy of Sciences of the United States of America, 104(45), 17575-17578 (2007-10-31)
We have shown previously that hydroxyl radicals (HO*) can be produced by H2O2 and halogenated quinones, independent of transition metal ions; however, the underlying molecular mechanism is still unclear. In the present study, using the electron spin resonance secondary radical
Tetrafluoro-p-benzoquinone
Essers M and Haufe G
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
Generation and spectroscopic characterization of the 2, 3, 5, 6-tetramethoxy-1, 4-benzosemiquinone reactive intermediate.
Mattar SM, et al.
Chemical Physics Letters, 352(1), 39-47 (2002)
Complexation Behavior of Binaphthol/Tetrafluoro-1, 4-benzoquinone Charge-Transfer Complex.
Imai Y, et al.
Crystal Growth & Design, 9(5), 2393-2397 (2009)
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