106860
乙酰基二茂铁
95%, solid
别名:
(乙酰基环戊二烯基)环戊二烯基, 1-二茂铁乙醇, 乙酰基二茂铁
产品名称
乙酰基二茂铁, 95%
质量水平
方案
95%
表单
solid
反应适用性
core: iridium
reagent type: catalyst
mp
81-83 °C (lit.)
SMILES字符串
[Fe].[CH]1[CH][CH][CH][CH]1.CC(=O)[C]2[CH][CH][CH][CH]2
InChI
1S/C7H7O.C5H5.Fe/c1-6(8)7-4-2-3-5-7;1-2-4-5-3-1;/h2-5H,1H3;1-5H;
InChI key
PHMAOJNZIFULOG-UHFFFAOYSA-N
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一般描述
乙酰二茂铁是一种有机金属化合物，可用作催化剂和起始材料，用于有机金属络合物的合成。
应用
乙酰二茂铁用于：
- 作为前体，在硼氢化钠存在下经由还原法合成1-二茂铁乙醇。
- 作为电活性物质，与MgO纳米颗粒联合修饰碳糊电极(CPE)用于检测L-半胱氨酸。
警示用语：
Danger
危险声明
危险分类
Acute Tox. 1 Dermal - Acute Tox. 2 Oral
储存分类代码
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 2
个人防护装备
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A series of bio-organometallic-hydrazones of the general formula [{(η5-C5H4)-C(R)=N-N(H)-C6H4-4-SO2NH2}]MLn(MLn = Re(CO)3, Mn(CO)3, FeCp; R=H, CH3) were prepared by reaction of formyl/acetyl organometallic precursors with 4-hydrazino-benzenesulphonamide. All compounds were characterized by conventional spectroscopic techniques (infra-red, 1H and 13C NMR, mass spectrometry and elemental
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Inclusion complex of acetylferrocene-thiosemicarbazone(TAF) with beta-cyclodextrin(beta-CD) has been prepared by using kneading method. Elemental analysis and the solubility determination proved that 1:1 inclusion complex has been formed. Characterization of the inclusion complex was studied by UV, FTIR, and X-ray diffractometry.
Ysaías J Alvarado et al.
Molecules (Basel, Switzerland), 10(2), 457-474 (2007-11-17)
The solvent effect on the position of the carbonyl vibrational stretching of acetylferrocene in aprotic media was studied in this work. The solvent-induced shifts in this organometallic compound were interpreted in terms of the alternative reaction field model(SCRF-MO) proposed by
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