106860
乙酰基二茂铁
95%, solid
别名:
(乙酰基环戊二烯基)环戊二烯基, 1-二茂铁乙醇, 乙酰基二茂铁
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关于此项目
经验公式（希尔记法）:
C12H12FeO
化学文摘社编号:
分子量:
228.07
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
215-043-2
MDL number:
产品名称
乙酰基二茂铁, 95%
InChI key
PHMAOJNZIFULOG-UHFFFAOYSA-N
InChI
1S/C7H7O.C5H5.Fe/c1-6(8)7-4-2-3-5-7;1-2-4-5-3-1;/h2-5H,1H3;1-5H;
SMILES string
[Fe].[CH]1[CH][CH][CH][CH]1.CC(=O)[C]2[CH][CH][CH][CH]2
assay
95%
form
solid
reaction suitability
core: iridium
reagent type: catalyst
mp
81-83 °C (lit.)
Quality Level
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Application
乙酰二茂铁用于：
- 作为前体，在硼氢化钠存在下经由还原法合成1-二茂铁乙醇。
- 作为电活性物质，与MgO纳米颗粒联合修饰碳糊电极(CPE)用于检测L-半胱氨酸。
General description
乙酰二茂铁是一种有机金属化合物，可用作催化剂和起始材料，用于有机金属络合物的合成。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 1 Dermal - Acute Tox. 2 Oral
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 2
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Magnetic NiFe2O4 nanoparticles: efficient, heterogeneous and reusable catalyst for synthesis of acetylferrocene chalcones and their anti-tumour activity
Applied Organometallic Chemistry, 30(11), 917-923 (2016)
Jing Zhang et al.
Guang pu xue yu guang pu fen xi = Guang pu, 25(10), 1568-1572 (2006-01-07)
Inclusion complex of acetylferrocene-thiosemicarbazone(TAF) with beta-cyclodextrin(beta-CD) has been prepared by using kneading method. Elemental analysis and the solubility determination proved that 1:1 inclusion complex has been formed. Characterization of the inclusion complex was studied by UV, FTIR, and X-ray diffractometry.
Thiol-Ene Chemistry of Vinylferrocene: A Simple and Versatile Access Route to Novel Electroactive Sulfur-and Ferrocene-Containing Model Compounds and Polysiloxanes
Martinez-Montero I, et al.
Macromolecules, 47(4), 1301-1315 (2014)
Martin Bertau et al.
Bioorganic & medicinal chemistry, 12(11), 2973-2983 (2004-05-15)
The bioavailability of lipophilic substrates is critical for biotransformations with isolated enzymes as well as with whole cells. With the example of a series of lipophilic ketones the suitability of saccharides as potent solubilisers for highly lipophilic substrates was demonstrated.
Ysaías J Alvarado et al.
Molecules (Basel, Switzerland), 10(2), 457-474 (2007-11-17)
The solvent effect on the position of the carbonyl vibrational stretching of acetylferrocene in aprotic media was studied in this work. The solvent-induced shifts in this organometallic compound were interpreted in terms of the alternative reaction field model(SCRF-MO) proposed by
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