106860
乙酰基二茂铁
95%, solid
别名:
(乙酰基环戊二烯基)环戊二烯基, 1-二茂铁乙醇, 乙酰基二茂铁
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关于此项目
经验公式（希尔记法）:
C12H12FeO
化学文摘社编号:
分子量:
228.07
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
215-043-2
MDL number:
产品名称
乙酰基二茂铁, 95%
InChI key
PHMAOJNZIFULOG-UHFFFAOYSA-N
InChI
1S/C7H7O.C5H5.Fe/c1-6(8)7-4-2-3-5-7;1-2-4-5-3-1;/h2-5H,1H3;1-5H;
SMILES string
[Fe].[CH]1[CH][CH][CH][CH]1.CC(=O)[C]2[CH][CH][CH][CH]2
assay
95%
form
solid
reaction suitability
core: iridium, reagent type: catalyst
mp
81-83 °C (lit.)
Quality Level
General description
乙酰二茂铁是一种有机金属化合物，可用作催化剂和起始材料，用于有机金属络合物的合成。
Application
乙酰二茂铁用于：
- 作为前体，在硼氢化钠存在下经由还原法合成1-二茂铁乙醇。
- 作为电活性物质，与MgO纳米颗粒联合修饰碳糊电极(CPE)用于检测L-半胱氨酸。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 1 Dermal - Acute Tox. 2 Oral
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 2
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Jeremie Brichet et al.
Journal of enzyme inhibition and medicinal chemistry, 35(1), 622-628 (2020-02-11)
A series of bio-organometallic-hydrazones of the general formula [{(η5-C5H4)-C(R)=N-N(H)-C6H4-4-SO2NH2}]MLn(MLn = Re(CO)3, Mn(CO)3, FeCp; R=H, CH3) were prepared by reaction of formyl/acetyl organometallic precursors with 4-hydrazino-benzenesulphonamide. All compounds were characterized by conventional spectroscopic techniques (infra-red, 1H and 13C NMR, mass spectrometry and elemental
Martin Bertau et al.
Bioorganic & medicinal chemistry, 12(11), 2973-2983 (2004-05-15)
The bioavailability of lipophilic substrates is critical for biotransformations with isolated enzymes as well as with whole cells. With the example of a series of lipophilic ketones the suitability of saccharides as potent solubilisers for highly lipophilic substrates was demonstrated.
Y N Vashisht Gopal et al.
Archives of biochemistry and biophysics, 376(1), 229-235 (2000-03-24)
Topoisomerase II is a major molecular target for a number of DNA-binding anticancer drugs. In the present study, we report topoisomerase II inhibition and anticancer activity by four substituted ferrocene derivatives which do not bind to DNA. The first derivative
Electrocatalytic determination of L-cysteine in the presence of tryptophan using carbon paste electrode modified with MgO nanoparticles and acetylferrocene
Gupta VK, et al.
International Journal of Electrochemical Science, 13, 4309-4318 (2018)
Sunita Yadav et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 78(1), 298-306 (2010-12-21)
Biological important complexes of boron(III) derived from 1-acetylferrocenehydrazinecarboxamide (L1H), 1-acetylferrocenehydrazinecarbothioamide (L2H) and 1-acetylferrocene carbodithioic acid (L3H) have been prepared and investigated using a combination of microanalytical analysis, melting point, electronic, IR, 1H NMR and 13C NMR spectral studies, cyclic voltammetry
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