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Merck
CN

106860

乙酰基二茂铁

95%, solid

别名:

(乙酰基环戊二烯基)环戊二烯基, 1-二茂铁乙醇, 乙酰基二茂铁

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关于此项目

经验公式(希尔记法):
C12H12FeO
化学文摘社编号:
分子量:
228.07
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
215-043-2
MDL number:
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产品名称

乙酰基二茂铁, 95%

Quality Level

assay

95%

form

solid

reaction suitability

core: iridium, reagent type: catalyst

mp

81-83 °C (lit.)

SMILES string

[Fe].[CH]1[CH][CH][CH][CH]1.CC(=O)[C]2[CH][CH][CH][CH]2

InChI

1S/C7H7O.C5H5.Fe/c1-6(8)7-4-2-3-5-7;1-2-4-5-3-1;/h2-5H,1H3;1-5H;

InChI key

PHMAOJNZIFULOG-UHFFFAOYSA-N

General description

乙酰二茂铁是一种有机金属化合物,可用作催化剂和起始材料,用于有机金属络合物的合成。

Application

乙酰二茂铁用于:
  • 作为前体,在硼氢化钠存在下经由还原法合成1-二茂铁乙醇。
  • 作为电活性物质,与MgO纳米颗粒联合修饰碳糊电极(CPE)用于检测L-半胱氨酸。


pictograms

Skull and crossbones

signalword

Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Oral

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 2

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Jeremie Brichet et al.
Journal of enzyme inhibition and medicinal chemistry, 35(1), 622-628 (2020-02-11)
A series of bio-organometallic-hydrazones of the general formula [{(η5-C5H4)-C(R)=N-N(H)-C6H4-4-SO2NH2}]MLn(MLn = Re(CO)3, Mn(CO)3, FeCp; R=H, CH3) were prepared by reaction of formyl/acetyl organometallic precursors with 4-hydrazino-benzenesulphonamide. All compounds were characterized by conventional spectroscopic techniques (infra-red, 1H and 13C NMR, mass spectrometry and elemental
Sunita Yadav et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 78(1), 298-306 (2010-12-21)
Biological important complexes of boron(III) derived from 1-acetylferrocenehydrazinecarboxamide (L1H), 1-acetylferrocenehydrazinecarbothioamide (L2H) and 1-acetylferrocene carbodithioic acid (L3H) have been prepared and investigated using a combination of microanalytical analysis, melting point, electronic, IR, 1H NMR and 13C NMR spectral studies, cyclic voltammetry
Y N Vashisht Gopal et al.
Archives of biochemistry and biophysics, 376(1), 229-235 (2000-03-24)
Topoisomerase II is a major molecular target for a number of DNA-binding anticancer drugs. In the present study, we report topoisomerase II inhibition and anticancer activity by four substituted ferrocene derivatives which do not bind to DNA. The first derivative



全球贸易项目编号

货号GTIN
106860-5G04061838674432
106860-25G04061838674425