10919
芴甲氧羰基异硫氰酸酯
≥98.0% (CHN)
别名:
9-芴甲基异硫氰酰甲酸酯, 9-芴甲氧羰基异硫氰酸酯
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关于此项目
经验公式（希尔记法）:
C16H11NO2S
化学文摘社编号:
分子量:
281.33
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
7930648
InChI
1S/C16H11NO2S/c18-16(17-10-20)19-9-15-13-7-3-1-5-11(13)12-6-2-4-8-14(12)15/h1-8,15H,9H2
SMILES string
O=C(OCC1c2ccccc2-c3ccccc13)N=C=S
InChI key
DHMYULZVFHHEHE-UHFFFAOYSA-N
assay
≥85% (coupling to amines), ≥98.0% (CHN)
solubility
ethanol: soluble
fluorescence
λex 264 nm; λem 313 nm
application(s)
peptide synthesis
functional group
Fmoc, amine, isothiocyanate
storage temp.
−20°C
Quality Level
Other Notes
由胺类化合物合成取代硫脲类化合物的试剂
Application
Fmoc isothiocyanate can be used:
- As a starting material in the preparation of biologically relevant pharmacophores named N-aryl-N′-carboalkoxy guanidines.
- In one of the intermediate steps for the synthesis of N-aryl-N-thiazolyl derivatives.
- To synthesize cyclic isothiourea derivatives as potent neuropeptide Y (NPY) Y1 receptor antagonists.
- To prepare 2-aminothiazoles, aminobenz-imidazole conjugated thiazoles, and thiazole derived cyclopeptides.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Two-step hantzsch based macrocyclization approach for the synthesis of thiazole-containing cyclopeptides
Nefzi A, et al.
The Journal of Organic Chemistry, 75(22), 7939-7941 (2010)
Solid-Phase Synthesis of N-Aryl-N′-Carboalkoxy Guanidines by the Mitsunobu Reaction of Fmoc-Guanidines
Robinson DE, et al.
Synthetic Communications, 34(15), 2743-2749 (2004)
Solid-Phase Synthesis of 2-Aminothiazoles.
Patrick C. Kearney et al.
The Journal of organic chemistry, 63(1), 196-200 (2001-10-25)
Diversity-oriented synthesis of N-aryl-N-thiazolyl compounds
Nefzi A and Arutyunyan S
Tetrahedron Letters, 51(37), 4797-4800 (2010)
Solid-phase synthesis of 2-aminothiazoles
Kearney PC, et al.
The Journal of Organic Chemistry, 63(1), 196-200 (1998)
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